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Publikováno v:
Chemical Physics Letters. 591:282-286
Thermal electron attachment processes in the mixtures of CH 3 CH 2 OH, CF 3 CH 2 OH, CF 3 CF 2 CH 2 OH, (CF 3 ) 2 CHOH and CH 3 CH(OH)CF 3 with carbon dioxide have been investigated using an electron Pulsed Townsend technique. Measurements were carri
Publikováno v:
Chemical Physics Letters. :25-28
In this Letter we report the results of the measurements of the rate coefficients for thermal attachment to several perfluoroethers namely perfluorodiglyme (C 6 F 14 O 3 ), perfluorotriglyme (C 8 F 18 O 4 ), perfluoropolyether (CF 3 –(OCF(CF 3 )CF
Autor:
Karola Graupner, Lucy Graham, Ilya I. Fabrikant, Hartmut Hotop, Janina Kopyra, I. Szamrej, Stephan Denifl, Philipp Sulzer, Thomas A. Field, Tilmann D. Märk, M. Braun, M.-W. Ruf, Paul Scheier
Publikováno v:
International Journal of Mass Spectrometry. 277:130-141
Results from a joint experimental and theoretical study of electron attachment to chloroform (CHCl3) molecules in the gas phase are reported. In an electron swarm study involving a pulsed Townsend technique with equal gas and electron temperatures, a
Autor:
W. Barszczewska, M. Foryś, Stanislav A. Pshenichnyuk, J. Wnorowska, V.S. Fal’ko, I. Szamrej, Janina Kopyra, Nail L. Asfandiarov
Publikováno v:
Radiation Physics and Chemistry. 76:1017-1025
Thermal electron attachment rate constants for CF 3 CHClCH 3 , CF 2 ClCFClCF 3 and CBrF 2 CH 2 CH 2 Br have been measured with electron swarm method. Corresponding rate constants are equal to 7.6×10 −11 , 5.5×10 −9 and 1.5×10 −8 cm 3 molecul
Autor:
Nail L. Asfandiarov, W. Barszczewska, J. Wnorowska, I. Szamrej, Janina Kopyra, S. A. Fal’ko, Stanislav A. Pshenichnyuk
Publikováno v:
The European Physical Journal D. 35:323-326
Thermal electron attachment rate constants for CH2ClCHBrCH3 and CH2ClCH2CH2Br have been measured using electron swarm method. Corresponding rate constants are equal to 3.5×10-10 and 2.5×10-10 cm3 molec-1 s-1, respectively. Parallely, negative ion m
Publikováno v:
Research on Chemical Intermediates. 27:699-707
Electron attachment processes in the mixture of haloethanes with carbon dioxide and nitrogen have been investigated. The rate constants for two-body processes have been measured. A link between rate constants and electron polarizabilities was demonst
Autor:
I. Szamrej
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry. 232:63-66
We have investigated thermal electron capture processes in the mixtures of halomethanes and carbon dioxide (in excess) using the electron swarm method. We have found that except the very slow second order reactions (single collision) there occur proc
Autor:
M. Forys, I. Szamrej
Publikováno v:
Progress in Reaction Kinetics and Mechanism. 23:117-143
Publikováno v:
Radiation Physics and Chemistry. 47:269-273
The first results for multi-body pressure dependent electron attachment processes in halomethanes are presented. The kinetics and mechanism of the thermal electron capture by CH 2 Cl 2 , CHFCl 2 and CF 2 Cl 2 in excess of CO 2 have been investigated.