Zobrazeno 1 - 10
of 131
pro vyhledávání: '"I. Schweizer"'
Autor:
Julia I. Schweizer, Clemens Bruhn, Nadine Weyer, Max C. Holthausen, Ulrich Siemeling, Myron Heinz
Publikováno v:
Angewandte Chemie (International Ed. in English)
The N‐heterocyclic silylene [{Fe(η5‐C5H4‐NDipp)2}Si] (1DippSi, Dipp=2,6‐diisopropylphenyl) shows an excellent combination of pronounced thermal stability and high reactivity towards small molecules. It reacts readily with CO2 and N2O, respec
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::10badcaaa51ee4678f4ebd944aa115c2
https://doi.org/10.1002/anie.202011691
https://doi.org/10.1002/anie.202011691
Autor:
Amelie Porzelt, Julia I. Schweizer, Ramona Baierl, Philipp J. Altmann, Max C. Holthausen, Shigeyoshi Inoue
Publikováno v:
Inorganics, Vol 6, Iss 2, p 54 (2018)
Reactivity studies of silyliumylidenes remain scarce with only a handful of publications to date. Herein we report the activation of S–H bonds in hydrogen sulfide by mTer-silyliumylidene ion A (mTer = 2,6-Mes2-C6H3, Mes = 2,4,6-Me3-C6H2) to yield a
Externí odkaz:
https://doaj.org/article/81c027ad0bfb401cb274578544f50127
Autor:
Julia I. Schweizer, Gary S. Nichol, Michael J. Cowley, Maximilian Menche, Max C. Holthausen, Martin W. Stanford
Publikováno v:
Stanford, M W, Schweizer, J I, Menche, M, Nichol, G S, Holthausen, M C & Cowley, M J 2019, ' Intercepting the Disilene-Silylsilylene Equilibrium ', Angewandte Chemie International Edition, vol. 58, no. 5, pp. 1329-1333 . https://doi.org/10.1002/anie.201810056
The equilibrium between disilenes (R2 Si=SiR2 ) and their silylsilylene (R3 Si-SiR) isomers has previously been inferred but not directly observed, except in the case of the parent system H2 Si=SiH2 . Here, we report a new method to prepare base-coor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c00890e38d0814a99143390e52bfc48
https://doi.org/10.1002/ange.201810056
https://doi.org/10.1002/ange.201810056
Autor:
Marcel Härterich, Max C. Holthausen, Merle Arrowsmith, Ivo Krummenacher, Holger Braunschweig, Myron Heinz, Julia I. Schweizer
Publikováno v:
Chemical Science
Mixed-base-stabilised chloroborylenes are easily accessed by twofold reduction of a cyclic (alkyl)(amino)carbene-supported trichloroborane in the presence of a second Lewis base, thus enabling fine-tuning of the electronic properties of the electron-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::da7a78cbce539fc90e16c3c8439c581f
https://doi.org/10.1039/c9sc01039d
https://doi.org/10.1039/c9sc01039d
Autor:
Max C. Holthausen, Matthias Otte, Igor Tkach, Serhiy Demeshko, Martin Diefenbach, Christian Limberg, Hendrik Verplancke, Sven Schneider, Jian Sun, Julia I. Schweizer, Christian Würtele, Christian Herwig
Publikováno v:
Chem
Summary In contrast to its lighter congener N2, neutral diphosphorus with a P≡P triple bond is a highly reactive species observable only in the gas phase and by matrix isolation. Previous stabilization efforts with Lewis bases (e.g., carbenes) or b
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e10a45403321e638fefe348b029266f7
http://resolver.sub.uni-goettingen.de/purl?gs-1/17864
http://resolver.sub.uni-goettingen.de/purl?gs-1/17864
Autor:
Max C. Holthausen, Norbert Auner, Tobias Santowski, Alexander G. Sturm, Julia I. Schweizer, Lioba Meyer
Publikováno v:
Chemistry - A European Journal. 24:17796-17801
A preparatively facile, highly selective synthesis of bifunctional monosilanes R2 SiHCl, RSiHCl2 and RSiH2 Cl is reported. By chlorination of R2 SiH2 and RSiH3 with concentrated HCl/ether solutions, the stepwise introduction of Si-Cl bonds is readily
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb0a2467d5325e520927ad61391f4de8
https://doi.org/10.1002/chem.201803921
https://doi.org/10.1002/chem.201803921
Autor:
Michael Bolte, Max C. Holthausen, Alexander G. Sturm, Matthias Berger, Timo Porsch, Norbert Auner, Julia I. Schweizer
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 644:982-988
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a43ced8b25612bcf361468e556fe5f70
https://doi.org/10.1002/zaac.201800163
https://doi.org/10.1002/zaac.201800163
Autor:
Julia I. Schweizer, Thorsten Felder, Alexander G. Sturm, Tobias Santowski, Max C. Holthausen, Lioba Meyer, Kenrick M. Lewis, Norbert Auner
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(36)
The industrial production of monosilanes Men SiCl4-n (n=1-3) through the Muller-Rochow Direct Process generates disilanes Men Si2 Cl6-n (n=2-6) as unwanted byproducts ("Direct Process Residue", DPR) by the thousands of tons annually, large quantities
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::596a60a208390b56d60f72a1f80c65c5
https://pubmed.ncbi.nlm.nih.gov/31026105
https://pubmed.ncbi.nlm.nih.gov/31026105
Publikováno v:
Swiss Medical Weekly, Vol 131, Iss 1112 (2001)
Externí odkaz:
https://doaj.org/article/337e617bad0b477dbc2784876596ddf5
Publikováno v:
Chemistry - A European Journal. 22:14328-14335
A detailed quantum-chemical study on the amine-induced disproportionation reaction of perchlorinated silanes to neo-Si5 Cl12 is reported. The key intermediate in the resulting mechanistic scenario is a dichlorosilylene amine adduct, which is in tune
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::395a996a3468616d1d11965aa31a734c
https://doi.org/10.1002/chem.201602724
https://doi.org/10.1002/chem.201602724