Zobrazeno 1 - 10
of 50
pro vyhledávání: '"I. M. Shermergorn"'
Autor:
L. A. Kudryavtseva, V. E. Bel'skii, B. E. Ivanov, Alla B. Mirgorodskaya, R. A. Shagidullina, L. Ya. Zakharova, I. M. Shermergorn
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1013-1017
The alkylation reaction kinetics of a series of amines of different structures by dimethyl phosphite have been studied. Two-parameter correlation equations have been deduced, relating reactivity to steric and inductive effects of substituent s attach
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 22:774-777
1. The IR spectra of certain fluoromethylthiophosphinic acid chlorides were studied. These compounds in solutions are characterized by an equilibrium of two conformera. 2. The conformers were identified on the basis of the dipole moments and IR spect
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 18:263-266
1. The kinetics of the alkaline and neutral aqueous hydrolysis of a number of phosphinic esters was investigated, and the rate constants and parameters of the Arrhenius equation were determined. 2. The rate constants of the reactions with water and t
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 18:566-569
The activity of bis-[N-alkyl-(or aryl)-aminomethyl] phosphonic acids of the general formula (RNHCH2)2 $$ \cdot P\begin{array}{*{20}c} {//} \\ \backslash \\ \end{array} \begin{array}{*{20}c} O \\ {OH} \\ \end{array} $$ in the interfacial polycondensat
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 18:324-330
1. In the condensation of bischloromethylphosphinic esters with sodiomalonic ester the anion of the latter may attack the bischloromethylphosphinic ester molecule at three reaction centers. 2. New phosphetane derivatives were synthesized, and some of
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 27:1033-1035
New phosphorus-containing iminoxyls in which the phosphorus atom is γ to the radical center were generated either electrochemically or photochemically, and the distribution of the spin density in them was established.
Autor:
I. M. Shermergorn, N. V. Ivasyuk
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 17:2262-2264
The reactions of bis(mereaptomethyl)phosphonic acid with alkyl and acyl halides were studied and a series of new thiomethyl phosphorus derivatives was synthesized.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 19:1326-1328
A study was made of the alkaline and water hydrolysis of bis(chloromethyl)phosphinothioic acid, and a mechanism was proposed for the first stage of this reaction.
Autor:
M. K. Il'ina, I. M. Shermergorn
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 17:1759-1761
Reaction of primary aliphatic and aromatic amines with bischloromethylphosphinic acid yielded a series of bis(N-alkyl(aryl)aminomethyl)phosphinic acids and the methacroylamides of several of them were obtained.
Autor:
I. V. Berezovskaya, E. V. Kuznetsov, É. Kh. Mukhametzyanova, L. A. Eliseeva, I. M. Shermergorn
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 17:1290-1292
1. A method of preparation of bis(allyloxymethyl)phosphonic acid and its esters was developed. 2. The ethyl ester of bis(allyloxymethyl)phosphonic acid is a low-toxicity compound with expressed depressive effects on the central nervous system.