Zobrazeno 1 - 10
of 38
pro vyhledávání: '"I. G. Pitt"'
Publikováno v:
Tetrahedron Letters. 35:1075-1078
Dimethyl octamethyltricyclo[4.2.2.0 2,5 ]deca-3,7,9-triene-7,8-dicarboxylate (Cookson's diester) ( 8 ) is rearranged thermally via a double Cope reaction to its ring-degenerate isomer ( 14 ). The structure of diester ( 8 ) (indirectly) and the rearra
Publikováno v:
ChemInform. 22
Photolysis of the specially synthesized substrate (39) leads to quantitative fragmentation into the phthalimide (56) and Dewar furan (4a). Dewar furan has only transient existence even at -65°, yet can be trapped effectively with isobenzofuran but n
Publikováno v:
ChemInform. 23
New approaches to the synthesis of rigid spacer molecules in which an oxygen-bridge bestows the facial polarity is described: attempts to couple 7-oxanorbornenes together using 1,3,4-oxadiazoles yields inverted, non linear products in a stereospecifi
Publikováno v:
ChemInform. 22
The reaction pathways of n-butoxy and s-butoxy radicals have been investigated by TLC and HPLC analysis of end products, particularly peroxides and carbonyl compounds. The butoxy radicals were produced by the pyrolysis of very low concentrations of t
Publikováno v:
ChemInform. 22
The synthesis of a photosubstrate (42) suitable for the production of a Dewar furan (46) containing a four-carbon bridge at the 1,4-position is described. The route to this product illustrates an example of transfer technology in synthesis, by using
Publikováno v:
ChemInform. 23
New spacer molecules are reported which contain alcohol functional groups at each end of the rigid carbocyclic framework. Simple coupling and extension reactions are used in their production thereby offering wide versatility in the shape, length and
Publikováno v:
ChemInform. 23
Publikováno v:
ChemInform. 25
Dimethyl octamethyltricyclo[4.2.2.0 2,5 ]deca-3,7,9-triene-7,8-dicarboxylate (Cookson's diester) ( 8 ) is rearranged thermally via a double Cope reaction to its ring-degenerate isomer ( 14 ). The structure of diester ( 8 ) (indirectly) and the rearra
Publikováno v:
ChemInform. 25
A new approach for the extension of [n]ladderanes is described which involves formation of an end-fused bicyclo[4.2.0]octadiene and its photoisomerisation to the related tricyclo[4.2.0.02,5] octene as the ladderane extension step. The protocol is ill
Publikováno v:
ChemInform. 25