Zobrazeno 1 - 10
of 50
pro vyhledávání: '"I. G. Dalla Lana"'
Publikováno v:
Industrial and Engineering Chemistry Research
During the oligomerization of ethylene over heterogeneous catalysts, the production of α-olefins may be lowered because of an accompanying deactivation of catalyst resulting from strong adsorption of products, by isomerization or by a tendency to co
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 34:3379-3387
A novel slurry reactor was used to investigate the copolymerization behavior of ethylene and 1-butene in the presence of 1 wt % Cr on Davison silica (Phillips-type) catalyst over the temperature range of 0–50°C, space velocity of about 0.0051 [m3
Publikováno v:
The Canadian Journal of Chemical Engineering. 73:220-227
The reaction rates for the hydrolysis of CS2 on either alumina (Kaiser 201) or titania (CRS 31) were measured at 150 kPa and from 270 to 330°C using a laboratory Berty reactor over ranges of water concentration (2–12 mol%) and CS2 concentration (0
Publikováno v:
The Journal of Physical Chemistry. 97:8005-8011
Prior studies on the adsorption of SO 2 on γ-alumina are not particularly revealing about the SO 2 -alumina surface interactions. Chemisorbed SO 2 on alumina was examined using a TPD-MS approach. The use of S 18 O 2 clearly demonstrated that both mo
Publikováno v:
The Canadian Journal of Chemical Engineering. 71:392-400
Autor:
P. A. Zielinski, I. G. Dalla Lana
Publikováno v:
Journal of Catalysis. 137:368-376
The onset of polymerization of ethylene on Cr/SiO 2 catalyst activated by high-temperature treatment was studied at room temperature using fast-scanning FTIR spectral measurements. Initial rapid adsorption of molecular ethylene on the pre-activated c
Publikováno v:
The Canadian Journal of Chemical Engineering. 70:516-522
Industrial alumina- and titania-based catalysts were tested for CS2 hydrolysis in a Berty reactor. Activated bauxite is the most active catalyst below 290°C and titanium oxide above 290°C. TGA experiments examining water desorption from 50°C to 55
Publikováno v:
Catalysis Letters. 15:145-153
Ethylene polymerization was carried out over both porous and non-porous 5 wt% Cr/silica catalysts in a slurry reactor. The polymerization was stopped at selected times to obtain samples for SEM and TEM characterization. Despite the different physical
Publikováno v:
Catalysis Letters. 13:331-339
High temperature treatment under vacuum or in a pure N2 atmosphere can be used instead of a reduction step to activate Cr/SiO2 catalysts used for ethylene polymerization. After this procedure, the Cr species active over a range of temperature has bee
Publikováno v:
Energy & Fuels. 4:599-604