Zobrazeno 1 - 10
of 17
pro vyhledávání: '"I. A. Torchinskii"'
Publikováno v:
Macromolecular Symposia. 278:96-104
Dynamic viscoelastic models of the system of two different interpenetrating polymer networks with different topology and type of interactions were used for calculating spectra of relaxation times of the system under consideration. It was shown, that
Publikováno v:
Macromolecular Symposia. 252:130-139
The viscoelastic coarse-grained dynamic model of a polymer network with rod-like particles included into the network is considered. The rods are regularly distributed in the network. The entanglements of rods in a polymer network lead to quasielastic
Publikováno v:
Applied Magnetic Resonance. 30:657-671
A theory of nuclear magnetic resonance relaxation of13C nuclei and nuclear Overhauser effect (NOE) of polymer networks with included rodlike particles is developed for the case when the length of each rod is comparable or greater than the average dis
Publikováno v:
Polymer Science Series A. 48:498-508
The dynamics of a rigid rod located between fixed junctions of a polymer network is studied. Three approaches are used in the solution of this problem. The first is based on the viscoelastic model, where a rigid rod is simulated by an elastic dumbbel
Publikováno v:
Macromolecular Symposia. 237:60-68
The theory of molecular mobility of a polymer network with included rod-like particles is developed. The case is considered when the length of rods is comparable or greater than the average distance between neighboring cross-links of the primary netw
Publikováno v:
Macromolecular Symposia. 220:139-154
We discuss the relaxation properties of polymer networks possessing either short-scale ordering caused by rigidity of network strands or long-scale liquid crystalline order. The main topics of the paper are the equilibrium and local dynamic propertie
Publikováno v:
Macromolecular Theory and Simulations. 13:303-317
Equilibrium and local dynamic properties- of ordered polymer networks with included rod-like particles are considered using a simplified network model. Lagrange multipliers in the equations of motion of rigid rods are replaced by their averaged value
The relaxation spectra of polymer networks with different types of topology, ordering, heterogeneity
Autor:
I. A. Torchinskii, Yuli Ya. Gotlib, V. A. Shevelev, Vladimir Toshchevikov, Andrew A. Gurtovenko
Publikováno v:
Macromolecular Symposia. 191:131-140
Many characteristic features of the relaxation spectra of the different types of polymer networks (meshlike and tree-like) manifesting in experimental behaviour are determined by manifold types of local and long-range irregularities or inclusions exi
Publikováno v:
Journal of Engineering Physics and Thermophysics. 76:480-487
The spectra of relaxation times of polymer meshes in the presence of various types of structural and dynamic heterogeneity have been considered. The influence of the orientation ordering of elements of macromolecules between the mesh nodes on the int
Autor:
Yu.Ya. Gotlib, I. A. Torchinskii
Publikováno v:
Polymer Science U.S.S.R.. 25:2128-2137
An evaluation is made of the local concentration in a crosslinked network system based on the model of Gaussian subchains. The dependence of the local concentration on the location of the portion of the network studied, the closeness of crosslinking