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Gas-phase chemistry of metal carbonyl anions: Reactions of Fe(CO)2− with methanol and its13C-, D- and18O-labelled analogues studied by fourier-transform ion cyclotron resonance mass spectrometry

Autor: N. M. M. Nibbering, I. K. Gregor, K.J. van den Berg, Steen Ingemann

Publikováno v: Rapid Communications in Mass Spectrometry. 7:769-773

The reactions of the metal dicarbonyl anion Fe(CO) with methanol and five of its isotopomers, namely CD3OH, CH3OD, CD3OH and CH318OH have been studied by the use of Fourier-transform ion cyclotron resonance mass spectrometry. Three competitive reacti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::239affcb3bb7fe4d1b991867c1dab070
https://doi.org/10.1002/rcm.1290070817

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Gas-phase chemistry of metal oxide anions: Reactions of dioxomanganate(III), MnO2−, and trioxomanganate(V), MnO3−, ions with monofluoro- and pentafluoro-aromatic compounds

Autor: Roel H. Fokkens, I. K. Gregor, N. M. M. Nibbering

Publikováno v: Organic Mass Spectrometry. 27:1013-1018

Gas-phase reactions of MnO2− and MnO3− ions with a series of monofluoro- and pentafluoro-aromatic compounds, i.e. C6H4FX with X = o-, m- and p-CHO and o-, m- and p-OH and C6F5Y with Y = OH, OCH3, CHO, CN, NO2, COCH3 and F, were studied at low pre

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c4d80c55156a925a404ec30c23be556d
https://doi.org/10.1002/oms.1210271010

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Gas-phase chemistry of first transition series carbonyl metallate ions: reactions with 13C-labelled carbonyl sulfide

Autor: R.C. Gregor, I. K. Gregor

Publikováno v: Inorganica Chimica Acta. 194:37-41

Fourier transform ion cyclotron resonance (FTICR) spectroscopic methods have been applied to examine the gas phase reactions of the metal carbonyl anions [metal(CO) 4 ] − , metalCr, Mn; [metal(CO) 3 ] − , metalCr, Mn, Fe; and [metal(CO) 2 ]

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::566edeee55d42b4a7e708543d547ab6d
https://doi.org/10.1016/s0020-1693(00)85820-x

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Chemistry of coordinatively unsaturated and electron deficient carbonyl metallate ions. Gas phase reactions of [Fe(CO)2]− with hydrocarbons

Autor: I. K. Gregor, R.C. Gregor

Publikováno v: Journal of Organometallic Chemistry. 415:257-263

The gas phase reactions of the metal dicarbonyl anion Fe(CO)2− with fifteen isotopically unlabelled, D- and 13C-labelled C2–6 alcohols have been studied by the use of Fourier transform ion cyclotron resonance mass spectroscopy. Several competitiv

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::16bc255619101c4f1d58a42e20db1e22
https://doi.org/10.1016/0022-328x(91)80123-2

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Gas-phase chemistry of first transition series carbonyl metallate ions, [Metal(CO)x]−: Reactions with13C- and18O-Labelled carbon dioxide. A Fourier-transform ion cyclotron resonance study

Autor: R. C. Gregor, I. K. Gregor

Publikováno v: Rapid Communications in Mass Spectrometry. 6:221-223

Gas-phase reactions between 13CO2 and C18O2 and a series of carbonyl metallate ions [Metal(CO)x]− with x=3, 4 for the metals chromium, manganese, iron and also x=2 for iron, have ben examined at low pressures by Fourier-transform ion cyclotron reso

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::abeb776d269adbd3214648dd2feed5ed
https://doi.org/10.1002/rcm.1290060314

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Gas-phase chemistry of metal oxide anions. The reactions of dioxomanganate(III), MnO2− and trioxomanganate(V), MnO3− ions with aliphatic alcohols

Autor: Roel H. Fokkens, I. K. Gregor, Nico M. M. Nibbering

Publikováno v: Rapid Communications in Mass Spectrometry. 5:368-370

Results of gas-phase reactions of MnO and MnO ions with a series of aliphatic C1C4 alcohols show that C2C4 primary alcohols are oxidized by MnO in reaction channels which involve proton abstraction and hydride-ion transfer, along with the appearance

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ea4bf7633f44a7996226e6088d73a8ca
https://doi.org/10.1002/rcm.1290050808

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Gas-phase reactions of transition metal carbonyl anions and atomic metal anions with nitrous oxide and dioxygen: oxygen atom transfer and ligand exchange in reactions with nitrous oxide

Autor: Klaas Jan van den Berg, I. K. Gregor, Steen Ingemann, Nico M. M. Nibbering

Publikováno v: Rapid Communications in Mass Spectrometry, 8. John Wiley and Sons Ltd

The gas-phase reactions of a series of metal carbonyl anions M(CO) (M=Cr, n=2–5; M=Mn, n=1–5; M=Fe, n=1–4) with nitrous oxide and dioxygen have been studied by use of Fourier-transform ion cyclotron resonance (FTICR) mass spectrometry. With nit

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ab1ce14c0a7c1973dc3c9e37a02425eb
https://doi.org/10.1002/rcm.1290081108

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