Zobrazeno 1 - 10
of 29
pro vyhledávání: '"Iñaki Osante"'
Publikováno v:
ARKIVOC, Vol 2007, Iss 4, Pp 206-219 (2006)
Externí odkaz:
https://doaj.org/article/1cf570d3b888466ea6704da0f16e07d3
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The novel enantiopure synthesis of protected proline-cysteine analogs by means of 1,3-dipolar cycloaddition of homochiral thiazolines and azomethine ylides is described. The important role of the oxidation state of the sulfur atom of the dipolarophil
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Here we report the diastereopure synthesis of a novel protected lanthionine derivative substituted with a cyclohexane ring as well as the diastereopure synthesis of an α-methyllanthionine derivative. By starting from enantiopure α,β-cyclohexane-su
Publikováno v:
European Journal of Organic Chemistry. 2019:4426-4435
This work was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) (project number CTQ2016–76155‐R), by the Fondos Europeos para el Desarrollo Regional (FEDER) and the Gobierno de Aragon (Group E34_R17; Zaragoza, Spain, Biolo
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Enantiopure 2-thia-4-azabicyclo[3.1.0]hexanes, which can be considered constrained cysteines, have been obtained from l-cysteine by application of the “self-regeneration of chirality” concept. The ...
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The reactivity of 2,3-dehydroproline and 2,3-dehydropipecolic acid methyl ester derivatives with S-nucleophiles in the thio-Michael addition reaction has been explored. The addition of triphenylmethanethiol and subsequent trityl cleavage led to the c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7c74a7d359538a68db51fe6cd36bdeee
http://hdl.handle.net/10261/187062
http://hdl.handle.net/10261/187062
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The behavior of homochiral 2,3-dihydrothiazoles, easily available from l-cysteine in Diels-Alder reaction with different dienes, "en route" to sterically constrained modified cystines, has been studied. The oxidation level of the sulfur atom of the h
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::14742cafa96de45a75546fb40c36157d
http://hdl.handle.net/10261/187076
http://hdl.handle.net/10261/187076
Autor:
Pavel Řezanka, David Díaz Díaz, Helena Sedláčková, Jakub Koktan, Iñaki Osante, Carlos Cativiela
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Many studies dealing with modified nanoparticles are based on the assumption that organic molecules form single-layer structure on their surface. In this work, we suggest a novel approach to study the important phenomenon of supramolecular chirality
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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This review provides an overview of the literature concerning the stereoselective synthesis of a large group of modified cysteines. The different synthetic approaches are classified according to the bonds formed to build the cysteine backbone skeleto
Autor:
Ricardo Rodríguez, Pilar García-Orduña, María Carmona, Daniel Carmona, José A. López, Iñaki Osante, Carlos Cativiela, Fernando J. Lahoz
Publikováno v:
Zaguán. Repositorio Digital de la Universidad de Zaragoza
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Digital.CSIC. Repositorio Institucional del CSIC
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Digital.CSIC. Repositorio Institucional del CSIC
The modified cysteine ligand, S-benzyl-α-methyl-l-cysteine (HL2), was prepared from l-cysteine hydrochloride methyl ester. The reaction of commercial S-benzyl-l-cysteine (HL1) or HL2 with the dimer, [{(η-CMe)RhCl}(μ-Cl)], gives rise to the cationi