Dioxygen activation at a mononuclear Cu(I) center Embedded in the calix [6]arene-Tren core

Autor: Stéphane Ménage, Ivan Jabin, Yves Le Mest, Yves Frapart, Bénédicte Douziech, Guillaume Izzet, Joceline Zeitouny, Olivia Reinaud, Huriye Akdas-Killig

Publikováno v: Journal of the American Chemical Society
Journal of the American Chemical Society, American Chemical Society, 2008, 130 (29), pp.9514. ⟨10.1021/ja8019406⟩
Journal of the American Chemical Society, 2008, 130 (29), pp.9514. ⟨10.1021/ja8019406⟩
Journal of the American Chemical Society, American Chemical Society, 2008, 130 (29), pp.9514. 〈10.1021/ja8019406〉

The reaction of a cuprous center coordinated to a calix[6]arene-based aza-cryptand with dioxygen has been studied. In this system, Cu(I) is bound to a tren unit that caps the calixarene core at the level of the small rim. As a result, although protec

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cdfb40f0a9d1b3f0bef82680f88f1fda
https://hal.archives-ouvertes.fr/hal-00378083