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pro vyhledávání: '"Hugo Tricas"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 4, Pp 512-515 (2019)
The molecular structure of the title compound 1-(2′,3′,5′,6′-tetrafluoro-4′-trifluoromethylphenyl)-closo-1,2-dicarbadodecaborane, C9H11B10F7, features an intramolecular ortho-F...H2 hydrogen bond [2.11 (2) Å], which is responsible for an o
Externí odkaz:
https://doaj.org/article/cff2d97e41334c889ff1dd6535262083
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 4, Pp 512-515 (2019)
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 4, Pp 512-515 (2019)
The title compound features an intramolecular hydrogen bond involving the acidic H atom bound to the cage C atom and an ortho-F atom of the heptafluorotolyl substituent.
The molecular structure of the title compound 1-(2′,3′,5′,6
The molecular structure of the title compound 1-(2′,3′,5′,6
Publikováno v:
Angewandte Chemie International Edition. 53:12222-12225
Three examples of the rare 8,1,2-closo-MC2B9 isomeric form of an icosahedral metallacarborane have been isolated as unexpected trace products in reactions. Seeking to understand how these were formed we considered both the nature of the reactions tha
Publikováno v:
Journal of Catalysis. 298:198-205
A wide range of monophosphite ligands was investigated in rhodium-catalyzed ethene hydroformylation. A stoichiometric gas mixture CO/H2/ethene 1:1:1 was used, the reaction being thus 100% atom economic. The reaction was found to be very selective and
Publikováno v:
ACS Catalysis. 3:128-137
Strong π-acceptor N-pyrrolylphosphoramidite and pyrrolylphosphine mono- and bidentante ligands were applied in ethene hydroformylation using a stoichiometric gas mixture CO/H2/ethene 1:1:1. Very fast reactions (TOF up to 29.5 × 103 mol mol–1 h–
Publikováno v:
Organometallics. 31:2523-2525
Reduction and metalation of 1,2-(4′-F3CC6F4)2-1,2-closo-C2B10H10 affords 4,1,12-MC2B10 compounds directly at room temperature with no evidence of intermediate 4,1,6- or 4,1,8-analogues. For M = CpCo this species is the only isolable product. The M
Autor:
Wing Y, Man, Sergey, Zlatogorsky, Hugo, Tricas, David, Ellis, Georgina M, Rosair, Alan J, Welch
Publikováno v:
Angewandte Chemie (International ed. in English). 53(45)
Three examples of the rare 8,1,2-closo-MC2B9 isomeric form of an icosahedral metallacarborane have been isolated as unexpected trace products in reactions. Seeking to understand how these were formed we considered both the nature of the reactions tha
Autor:
Stuart MacGregor, Victoria Petrie-Armstrong, David Ellis, Hugo Tricas, Dmitry S. Perekalin, Georgina M. Rosair, Fraser MacIntosh, Fabien Herisse, Brian W. Hutton, David McKay, Alan J. Welch
Publikováno v:
Chemical communications (Cambridge, England). (42)
The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C–C connectivities.
Autor:
Hugo Tricas, Ivan V. Glukhov, Franco Laschi, David Ellis, Piero Zanello, Marta Colon, Fulvio Rossi, Georgina M. Rosair, Stuart MacGregor, Alan J. Welch, David McKay
Publikováno v:
Dalton Transactions. 40:4200
The icosahedral carboranes 1-C(6)F(5)-2-Ph-1,2-closo-C(2)B(10)H(10) (1), 1-(4'-F(3)CC(6)H(4))-2-Ph-1,2-closo-C(2)B(10)H(10) (2), 1,2-(4'-F(3)CC(6)H(4))(2)-1,2-closo-C(2)B(10)H(10) (3), 1-(4'-H(3)CC(6)F(4))-2-Ph-1,2-closo-C(2)B(10)H(10) (4), 1-(4'-F(3
Autor:
Brian W. Hutton, Fraser MacIntosh, David Ellis, Fabien Herisse, Stuart A. Macgregor, David McKay, Victoria Petrie-Armstrong, Georgina M. Rosair, Dmitry S. Perekalin, Hugo Tricas, Alan J. Welch
Publikováno v:
Chemical Communications; Nov2008, Vol. 2008 Issue 42, p5345-5347, 3p