Zobrazeno 1 - 10
of 73
pro vyhledávání: '"Hugh Burrows"'
Publikováno v:
Angewandte Chemie (International ed. in English). 46(12)
Publisher Summary This chapter provides a brief description of unimolecular reactions that is one of the most conceptually simple reactions in chemistry and presents several mechanisms that are helpful in understanding these reactions. The mechanism
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::665314832e6aa06bd4e5b3d606e86fb7
https://doi.org/10.1016/b978-044452186-6/50008-0
https://doi.org/10.1016/b978-044452186-6/50008-0
Publisher Summary This chapter provides an overview of chain reactions. In chain reactions, free radicals bring about chemical processes, such as abstraction when they react with a molecule, producing new atoms and radicals, which can then bring abou
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::96895811f8b7ab44320d6f3653a3069c
https://doi.org/10.1016/b978-044452186-6/50012-2
https://doi.org/10.1016/b978-044452186-6/50012-2
This chapter discusses acid–base catalysis and proton-transfer reactions. Proton-transfer (PT) reactions lie at the heart of the mechanistic definition of acid and base. An acid is a molecular entity capable of donating a proton and a base is anoth
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e30859791d5b3542db0861e0d7d86fa2
https://doi.org/10.1016/b978-044452186-6/50013-4
https://doi.org/10.1016/b978-044452186-6/50013-4
This chapter presents a transition-state theory (TST) that has become the paradigm for interpreting the rates of chemical processes and their dependence on temperature, medium, structure, and other parameters. The TST is known as a statistical-mechan
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::149ccee1a327724860f1e7a5750780e2
https://doi.org/10.1016/b978-044452186-6/50006-7
https://doi.org/10.1016/b978-044452186-6/50006-7
This chapter discusses the factors involved in determining the rates of chemical reaction. The velocities of elementary chemical reactions depend on a number of factors, in particular the nature of the reactants, concentrations or pressures, temperat
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https://explore.openaire.eu/search/publication?articleId=doi_________::54aa69ea09da438ce5bbaabeff1527e1
https://doi.org/10.1016/b978-044452186-6/50002-x
https://doi.org/10.1016/b978-044452186-6/50002-x
This chapter deals with the transitions between electronic states. The methods of chemical kinetics are applied to the study of transitions between the different electronic states. Such transitions may occur either with the absorption or emission of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f2768c09f00a8d70246995db70a07be6
https://doi.org/10.1016/b978-044452186-6/50015-8
https://doi.org/10.1016/b978-044452186-6/50015-8