Výsledky vyhledávání - "Hubert Theil"

A Comprehensive Study on Triplesalen‐Based [Mn III 6 Fe III ] 3+ and [Mn III 6 Fe II ] 2+ Complexes: Redox‐Induced Variation of Molecular Magnetic Properties

Autor: Veronika Hoeke, Jürgen Schnack, Hubert Theil, Maik Heidemeier, Thorsten Glaser, Anja Stammler, Thomas Weyhermüller, Hartmut Bögge, Erich Krickemeyer

Publikováno v: European Journal of Inorganic Chemistry. 2013:4398-4409

The synthesis and structural, mass spectrometric, FT-IR, Mossbauer, and UV/Vis spectroscopic, electrochemical, and DC and AC magnetic properties of three [(Mn6FeIII)-Fe-III](3+) (short for [{(talentBu2)Mn-3(III)}(2){Fe-III(CN)(6)}](3+)) compounds {[(

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9d007bd9eb5a92489380fa5d06b656e1
https://doi.org/10.1002/ejic.201300400

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From triplesalen to triplesalacen: Synthesis spectroscopic, redox, and magnetic properties of the trinuclear CuII3 triplesalacen complex

Autor: Maik Heidemeier, Hartmut Bögge, Hubert Theil, Stephan Walleck, Thorsten Glaser, Gabriele Heinze-Brückner, Anja Stammler

Publikováno v: Inorganica Chimica Acta. 363:4287-4294

The tris(tetradentate) triplesalacen ligand H6talacen and its trinuclear copper complex, namely [(talacen)CuII3], were synthesized and its molecular and electronic structure determined. The ligand is prepared by the triple condensation of 2,4,6-trisa

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ad621e7d4b8a478732ea2a984b5e4f54
https://doi.org/10.1016/j.ica.2010.06.054

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A streamlined synthesis of extended thiophloroglucinol ligands and their trinuclear Ni-3(II) complexes

Autor: Bastian Feldscher, Hartmut Bögge, Thorsten Glaser, Anja Stammler, Hubert Theil

A protocol for the synthesis of trinucleating C3-symmetric ligands based on a central meta-phenylene bridging 1,3,5-trimercaptobenzene (thiophloroglucinol) backbone has been established. The key compound turned out to be the trialdehyde obtained from

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19d7786a2ea35da45e665544c90087c6
https://doi.org/10.1039/c3dt53457j

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Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes

Autor: Hubert Theil, Hartmut Bögge, Thorsten Glaser, Anja Stammler, Bastian Feldscher

An unprecedented trinucleating ligand with a central 1,3,5-trimercaptobenzene unit and its trinuclear Cu(II)(3) complex are presented. The high covalency of the difficult-to-realize Cu(II)-SR bond provides an order of magnitude increase in the supere

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b73a61acfbcb5e1a53d05228e06895c0
https://pub.uni-bielefeld.de/record/2544286

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ChemInform Abstract: Spin Polarization in 1,3,5-Trihydroxybenzene-Bridged First-Row Transition Metal Complexes

Autor: Maik Heidemeier, Hubert Theil, Thorsten Glaser

Publikováno v: ChemInform. 41

The late Olivier Kahn formulated a research objective for molecular magnetism: ‘The normal trend for the molecular state is the pairing of electrons […] with a cancellation of the electron spins. The design of a molecule-based magnet requires tha

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::48bd3d7440451d60e248fe28010e32ae
https://doi.org/10.1002/chin.201033227

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A MnIII triplesalen-based 1D pearl necklace: exchange interactions and zero-field splittings in a C-3-symmetric Mn-6(III) complex

Autor: Hubert Theil, Hartmut Bögge, Anja Stammler, Thorsten Glaser, Maik Heidemeier, Jürgen Schnack

The reaction of the tert-butyl-substituted triplesalen ligand H(6)talen(t-Bu(2)) with 2.8 equivalents of Mn(OAc)(2) x 4 H(2)O in MeOH in the presence of NaBPh(4) results in the formation of the one-dimensional (1D) coordination polymer {[{(talen(t-Bu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cd12b4d9b359ca9b63f5c6d882d2ff4f
https://pub.uni-bielefeld.de/record/1589403

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A Triple Newman-Kwart Rearrangement at a Fully Substituted Benzene Ring

Autor: Roland Fröhlich, Hubert Theil, Thorsten Glaser

Dedicated to Professor Hubert Schmidbaur on the occasion of his 75 th birthday The Newman-Kwart rearrangement of O-thiocarbamates to S-thiocarbamates is a versatile method for the conversion of phenols into thiophenols. The triple rearrangement of th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4e2d8cdea09dab7b3fa14c6299b0efa3
https://doi.org/10.1515/znb-2009-11-1250

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Spin-polarization in 1,3,5-trihydroxybenzene-bridged first-row transition metal complexes

Autor: Hubert Theil, Maik Heidemeier, Thorsten Glaser

The late Olivier Kahn formulated a research objective for molecular magnetism: 'The normal trend for the molecular state is the pairing of electrons [...] with a cancellation of the electron spins. The design of a molecule-based magnet requires that

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::05aba928ccd7a299f1f92a3962c2a1a3
https://pub.uni-bielefeld.de/record/1636484

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