Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Huaiju Wang"'
Publikováno v:
Nature Reviews Chemistry. 6:745-755
Publikováno v:
Chemical Science
This review summarizes recent advances in the catalytic generation of alkoxy radicals from unfunctionalized alcohols and highlights current methods for O–H bond activation.
Alkoxy radicals have long been recognized as powerful synthetic interm
Alkoxy radicals have long been recognized as powerful synthetic interm
We report a general protocol for the light-driven isomerization of cyclic aliphatic alcohols to linear carbonyl compounds. These reactions proceed via proton-coupled electron transfer (PCET) activation of alcohol O–H bonds followed by subsequent C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67f9dc49a6b2d86790dfae7efbd102c5
https://europepmc.org/articles/PMC6508595/
https://europepmc.org/articles/PMC6508595/
We report a new photocatalytic protocol for the redox-neutral isomerization of cyclic alcohols to linear ketones via C–C bond scission. Mechanistic studies demonstrate that key alkoxy radical intermediates in this reaction are generated via the dir
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8527a6f08d5809625011e85ec54b4757
https://europepmc.org/articles/PMC5110324/
https://europepmc.org/articles/PMC5110324/
Publikováno v:
Chemical Science
We report a simple protocol for the transition metal-free, visible-light-driven conversion of 1,3-diketones to tetra-substituted furan skeleton compounds in carbon dioxide (CO2) atmosphere under mild conditions. It was found that CO2 could be incorpo