Zobrazeno 1 - 3
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pro vyhledávání: '"Hsin Hung Chi"'
Publikováno v:
Journal of the Chinese Chemical Society. 60:725-734
The reactions of two types of EFe3-based acyl clusters [EFe3(CO)9C(O)C(H)CCH2)]− (E = S, 1; Se, 2; Te, 3) with different electrophiles have been systematically studied and compared. When the sulfur-substituted allylcarbonyl Fe3-cluster [Fe3(CO)9{μ
Publikováno v:
Inorganic Chemistry. 39:5561-5564
The synthesis of the acyl cluster complex [Et4N][(μ3-Se)Fe3(CO)9((μ3-η1,η1,η3-C(O)CHCCH2)] and isolation of the trans and cis isomers of the Fischer-type cluster carbene (μ3-Se)Fe3(CO)9(μ3-η1,η1,η3-C(OMe)CHCCH2) are described.
Autor:
Miao Hsing Hsu, Yu Xin Huang, Jiann Jang Cherng, Szu Wei Chen, Chia Yeh Miu, Hsin Hung Chi, Minghuey Shieh
Publikováno v:
New Journal of Chemistry. 35:2442
When the μ3-sulfido triiron cluster [SFe3(CO)9]2− was treated with BrCH2C(O)OCH3 in MeCN, the ester-functionalized complex [SFe3(CO)9(CH2C(O)OCH3)]− (1) was obtained. Cluster 1 displays a SFe3 tetrahedral core with one of the Fe atoms bonded to