Zobrazeno 1 - 10
of 48
pro vyhledávání: '"Horst Stratemeier"'
Publikováno v:
Inorganic Chemistry. 52:10481-10499
The temperature dependence of the structures of a wide range of mixed-cation Tutton’s salts of general formula K2xRb2–2x[Cu(H2O)6](SeO4)2 has been determined over the temperature range 90 to 320 K. Crystals with a high proportion of potassium ado
Autor:
David C. R. Hockless, Allan H. White, Horst Stratemeier, Michael A. Hitchman, Brian W. Skelton
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 633:2004-2008
Magnesium methoxyacetate crystallizes from aqueous solution as a dihydrate, isomorphous with its nickel(II) and copper(II) counterparts, the six-coordinate metal atoms being disposed on crystallographic inversion centres in space group P21/n. The cad
Publikováno v:
Inorganic Chemistry. 45:1021-1031
The temperature dependence of the structure of the mixed-anion Tutton salt K2[Cu(H2O)6](SO4)(2x)(SeO4)(2-2x) has been determined for crystals with 0, 17, 25, 68, 78, and 100% sulfate over the temperature range of 85-320 K. In every case, the [Cu(H2O)
Publikováno v:
Crystal Growth & Design. 3:403-407
The influence of pressure on the unit cell parameters of deuterated ammonium copper(II) sulfate hexahydrate at various temperatures from 50 to 325 K obtained from pulsed neutron powder diffraction ...
Autor:
Godfrey S. Beddard, Charles J. Simmons, Michael A. Hitchman, Horst Stratemeier, Malcolm A. Halcrow, Marcelo P. de Miranda
Publikováno v:
Dalton Transactions. :1028-1032
The temperature dependence of the bond lengths in the high temperature phase of [Cu(L)2][BF4]2 (L = 2,6-dipyrazol-1-ylpyridine) may be interpreted satisfactorily using a model of dynamic, Jahn–Teller (JT) vibronic coupling. The geometries of the th
Autor:
Brian N. Figgis, Charles J. Simmons, Michael A. Hitchman, Alexandre N. Sobolev, Mark J. Riley, Horst Stratemeier
Publikováno v:
Acta Crystallographica Section B Structural Science. 56:438-443
The crystal structures of the Tutton salts (NH4)2-[Cu(H2O)6](SO4)2, diammonium hexaaquacopper disulfate, formed with normal water and isotopically substituted H2 18O, have been determined by X-ray diffraction at 9.5 K and are very similar, with Cu—
Publikováno v:
Applied Magnetic Resonance. 19:121-131
The powder electron paramagnetic resonance spectra of ∼1% Cu doped into [Zn(bipy)2(NO2)]NO3 and [Zn(bipyam)2(NO2)]NO3, bipy = 2,2′-bipyridyl, bipyam = 2,2′-bipyridylamine, over the temperature range 4.2–300 K are reported. For [Zn/Cu(bipy)2(N
Autor:
Larry R. Falvello, Milagros Tomás, Arthur J. Schultz, D. M. Young, Isabel Pascual, Esteban P. Urriolabeitia, Michael A. Hitchman, Horst Stratemeier, Fernando Palacio
Publikováno v:
Journal of the American Chemical Society. 121:2808-2819
The six-coordinate coordination complex trans-[Ni(cyan-{kappa}N){sub 2}(NH{sub 3}){sub 4}] has been characterized in the solid state by X-ray and neutron diffraction at temperatures ranging from 11 to 298 K, by electronic spectroscopy over the temper
Publikováno v:
Journal of the American Chemical Society. 121:1488-1501
The crystal structure of the deuterated Tutton salt (ND4)2[Cu(D2O)6](SO4)2 determined by X-ray diffraction at several temperatures between 100 and 321 K is reported. The intermediate and longest Cu−O bond lengths of the Jahn−Teller distorted octa