Zobrazeno 1 - 10
of 56
pro vyhledávání: '"Hollie K. Jacobs"'
Publikováno v:
Tetrahedron Letters. 54:630-634
The HOPO vinyl sulfonamide 3 and the corresponding HOPO acrylamide 10 were easily prepared by short synthetic sequences. Investigation of the aza-Michael reactions of these linkers showed that they proceed at a higher rate in solvent systems containi
Publikováno v:
Tetrahedron. 68:10030-10039
Synthetic approaches to mixed ligand chelators on readily available tert-butylphenol–formaldehyde oligomer, PFO, scaffolds were examined. In a promising approach, tris and tetraphenol oligomers were selectively mono or di protected using tert-butyl
Publikováno v:
Tetrahedron Letters. 53:6367-6371
Two novel bifunctional N -methylhydroxamate–isocyanate linkers 20 and 21 were prepared in good yield and high purity from the corresponding amine salts using a biphasic reaction with phosgene. The facile ring opening reaction of N -Boc lactams usin
Publikováno v:
Tetrahedron. 67:2206-2214
N-Alkyl-N-benzyloxy carbamates, 2, undergo facile intramolecular cyclization with a variety of carbon nucleophiles to give functionalized five- and six-membered protected cyclic hydroxamic acids, 3, in good to excellent yields. This method can be ext
Publikováno v:
Tetrahedron Letters. 52:887-890
The intramolecular cyclizations of oxazolidinones with carbanions adjacent to sulfones, sulfoxides, and phosphonates proceed in high yields to obtain functionalized γ and δ lactams. The chiral oxazolidinone precursors can be readily synthesized fro
Publikováno v:
Synthesis. 2011:57-64
The HOPO sulfonamide reagent, 3, was prepared from commercial 2,3-dihydroxypyridine in four steps in good yields. Sulfonamide 3 readily underwent selective alkylation with dibromides in the presence of base or could be coupled to alcohols using Mitsu
Autor:
Krishnaswamy Devanathan, Patricia C. Wilkins, Jennifer A. Bell, Aravamudan S. Gopalan, Hollie K. Jacobs
Publikováno v:
Tetrahedron Letters. 48:8029-8033
A convenient synthesis of a variety of substituted N -hydroxysulfamides from chlorosulfonyl isocyanate is reported. Alkyl groups can be introduced selectively on the N -Boc nitrogen of key intermediates 1a or 1b using the Mitsunobu reaction with alco
Autor:
Aravamudan S. Gopalan, Gloria Martinez, Hollie K. Jacobs, Sumathi Chittamuru, Timothy N. Lambert
Publikováno v:
Tetrahedron Letters. 48:567-571
The reactions of the electrophilic iminium ester mesylate salt 1 with alcohols, phenols and thiols has been investigated. In the presence of base, thiols, phenols and thiophenol react with 1 to give the corresponding ether linked HOPO derivatives in
In contrast to 2,3-dihydroxypyridine, the 3-benzyloxy protected derivative, 2, undergoes facile alkylation at ambient temperatures with a variety of functionalized alkyl halides in good yields. This alkylation has been used to prepare a number of lin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e666eb026b03b4e09f43e54b06859678
https://europepmc.org/articles/PMC4665106/
https://europepmc.org/articles/PMC4665106/
Publikováno v:
Reactive and Functional Polymers. 55:109-119
A major goal of our research program is to develop water soluble chelating polymers for the selective separation of trivalent cations such as iron(III) and tetravalent actinide ions such as Th(IV) or Pu(IV) from aqueous, radioactive waste streams. As