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pro vyhledávání: '"Hitosi Nozaki"'
Autor:
Kazuhiko Takai, Hitosi Nozaki
Publikováno v:
Proceedings of the Japan Academy, Series B. 76:123-131
One important theme in organic synthesis is to accomplish highly selective transformations under mild conditions, which yield only desirable products. During the past two decades, we have developed several useful tools to achieve this, i.e., organoch
Autor:
Kiitiro Utimoto, Mizuka Tagashira, Kazuhiko Takai, Tooru Kuroda, Hitosi Nozaki, Koichiro Oshima
Publikováno v:
Journal of the American Chemical Society. 108(19)
Publikováno v:
The Journal of Organic Chemistry. 58:4971-4978
Carbonyls and acetals are converted to 1,3-dithianes and -dithiolanes upon treatment with 2-stanna-1,3-dithianes and -dithiolanes under catalysis by organotin triflates. In these competition reactions, various types of carbonyls and acetals are diffe
Publikováno v:
Tetrahedron. 49:3065-3074
1, n -Diol diacetates (n = 2,3,4) are selectively converted into the corresponding monoacetates by distannoxane-catalyzed transesterification. Such unique selectivity is not encountered with 1, n -diol diacetates where n ≥ 5. A great difference in
Autor:
Hitosi Nozaki
Publikováno v:
Journal of Synthetic Organic Chemistry, Japan. 51:950-954
Publikováno v:
ChemInform. 23
1,4-Addition of methoxy(phenylthio)(trimethylsilyl)methyllithium to 4-siloxy-2-cyclopentenone followed by in situ alkylation of the resultin enolate provides a versatile intermediate for synthesis of prostaglandins.
Autor:
Hitosi Nozaki
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
The mechanism of the Mukaiyama reaction has never been examined from the standpoint of electron transfer. We conclude here that the Lewis mediated electron transfer from hindered ketene silyl acetals to α-enones plays an essential role in connecting