Zobrazeno 1 - 10
of 46
pro vyhledávání: '"Hitoshi Ube"'
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-10 (2024)
Abstract Chemical etching of nano-sized metal clusters at the atomic level has a high potential for creating metal number-specific structures and functions that are difficult to achieve with bottom-up synthesis methods. In particular, precisely etchi
Externí odkaz:
https://doaj.org/article/8160e09562b24e9e8f8da06d28d0953b
Publikováno v:
ACS Organic & Inorganic Au, Vol 3, Iss 6, Pp 371-376 (2023)
Externí odkaz:
https://doaj.org/article/800aeab92b7f4bdf95504c753a2f0503
Autor:
Zhen Lei, Mizuki Endo, Hitoshi Ube, Takafumi Shiraogawa, Pei Zhao, Koichi Nagata, Xiao-Li Pei, Tomoya Eguchi, Toshiaki Kamachi, Masahiro Ehara, Takeaki Ozawa, Mitsuhiko Shionoya
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-9 (2022)
Photoluminescent gold clusters have unique chemical and physical properties based on their perturbed electronic structures. Here, the authors report the synthesis of carbon-centered Au(I)-Ag(I) clusters with high phosphorescence quantum yields using
Externí odkaz:
https://doaj.org/article/a63e97917dd8476a9f484dc1a0ebacf4
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
Unlike traditional chiral metal complexes, which typically contain chiral ligands, in chiral-at-metal complexes chirality originates from a stereogenic metal center bound to achiral ligands. Herein, the authors use an unsymmetric tridentate ligand to
Externí odkaz:
https://doaj.org/article/427f73a60f234df092d7299bc432f25a
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-6 (2017)
In metal-based molecular motors, the motion is generally triggered by changes in the ligand coordination around the metal centre. Here, the authors synthesize a molecular gear that switches between states through photo- and thermally driven geometric
Externí odkaz:
https://doaj.org/article/84189335465e41d2b20629f1d43e1367
Publikováno v:
Dalton Transactions. 52:3295-3299
We report experimental data and theoretical analyses of the synthesis, structure, and properties of racemic tetrahedral “chiral-at-vanadium(v)” complexes with an unsymmetrical achiral phenolic bidentate ligand.
Publikováno v:
Journal of Synthetic Organic Chemistry, Japan. 80:498-505
Autor:
Xiao-Li Pei, Pei Zhao, Hitoshi Ube, Zhen Lei, Koichi Nagata, Masahiro Ehara, Mitsuhiko Shionoya
Publikováno v:
Journal of the American Chemical Society. 144:2156-2163
Publikováno v:
Chemical Science.
The properties of metal clusters are highly dependent on their molecular surface structure.
Publikováno v:
Bulletin of the Chemical Society of Japan. 94:1324-1330
Ubiquitous intramolecular aurophilic interactions in gold clusters have usually been assigned as the main determinants of their molecular geometry and various properties. By utilizing N-heterocycli...