Zobrazeno 1 - 10
of 96
pro vyhledávání: '"Hiroto Nagaoka"'
Publikováno v:
Tetrahedron Letters. 56:5941-5944
Novel pyridinium dichromate (PDC) catalyzed oxidative rearrangement for the conversion of tertiary allylic alcohols to s-substituted enones is described. Using a catalytic amount of PDC with PhI(OAc) 2 as a co-oxidant in the presence of magnesium sul
Autor:
Hiroshi Kogen, Shinya Watanabe, Kokoro Nagasawa, Atsushi Kishida, Kenta Tendo, Kazuma Matsunaga, Kazuhiko Takatori, Hiroto Nagaoka, Shoya Ota
Publikováno v:
Organic letters. 19(14)
Direct conversion of methylenebicyclo[4.2.0]octanone to methylenebicyclo[3.2.1]octanol by a Sm(II)-induced 1,2-rearrangement with ring expansion of the methylenecyclobutane is described. Three conditions were optimized to allow the adaptation of this
Publikováno v:
ChemInform. 47
Novel pyridinium dichromate (PDC) catalyzed oxidative rearrangement for the conversion of tertiary allylic alcohols to s-substituted enones is described. Using a catalytic amount of PDC with PhI(OAc) 2 as a co-oxidant in the presence of magnesium sul
Autor:
Atsushi Kishida, Hiroto Nagaoka
Publikováno v:
Tetrahedron Letters. 49:6393-6397
Cascade reaction involving reductive cyclization, Dieckmann condensation, and lactonization of E- and Z-dimethyl 2-methyl-8-oxoundec-2-enedioates and Z-dimethyl 2-methyl-7-oxodec-2-enedioate with samarium(II) iodide was found to stereospecifically pr
Publikováno v:
Journal of Synthetic Organic Chemistry, Japan. 65:665-676
Reactive free radicals have wide applications in organic synthesis due to their remarkable chemical properties that allow useful molecular transformations. The present review covers the author's recent studies on the utilization of radical species in
Autor:
Ikuo Shinohara, Hiroto Nagaoka
Publikováno v:
Tetrahedron Letters. 45:1495-1498
Novel ring-expansion reaction of 1,2-cyclobutanedicarboxylates with Sm(II) in the presence of HMPA with a catalytic amount of methanol was found to provide 2-oxocyclopentanecarboxylates.
Publikováno v:
Tetrahedron Letters. 43:8587-8590
Atom-transfer radical annulation of diene derived from d -glucose under Kharasch conditions provided access to the fully functionalized CD ring system of paclitaxel.
Publikováno v:
Synlett. 2002:0227-0230
An efficient method was established for the synthesis of the optically active bicyclo[4.2.1]nonane segment of mediterraneols using diastereoselective sequential Michael reaction and then retro-aldol reaction.
Publikováno v:
Tetrahedron Letters. 41:5923-5926
A new route to the synthesis of an optically active illudane skeleton from ( R )-(−)-pantolactone ( 4 ) is established. The tricyclic ring system was constructed by Michael–Michael-elimination reaction of the enolate of (3 S ,5 R )-3-( tert -buty
Publikováno v:
Tetrahedron Letters. 40:5215-5218
Two complementary methods for the construction of the ring system of CP-263,114 ( 1 ), one relying on the Grob fragmentation reaction and the other on a sequential photolytic alkoxy radical fragmentation-reduction, are described.