Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Hirotaka Takeshima"'
Publikováno v:
The Journal of Organic Chemistry. 80:5407-5414
The current work describes the marked rate of acceleration caused by phosphine ligands on the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C(sp(3))-H bonds. The reactivity was affected by the steric and electronic natur
Publikováno v:
ChemInform. 46
The optimal phosphine ligands are found for the rhodium-catalyzed synthesis of 2,3-dihydro-1H-benzo[b]siloles (II) and 2,3-dihydro-1H-benzo[b]germole (IV).
Publikováno v:
ChemInform. 46
The silylation of azulene with various hydrosilanes proceeds with excellent regioselectivity to form 2-silylazulenes without the need for any directing groups.
Iridium-catalyzed dehydrogenative silylation of azulenes based on regioselective C-H bond activation
Publikováno v:
Organic letters. 17(7)
Use of an iridium catalyst allowed the efficient dehydrogenative functionalization of C–H bonds of azulenes with the production of hydrogen as the sole byproduct. The reaction occurred with excellent chemo- and regioselectivities to provide 2-silyl
Autor:
Akiyoshi Komura, Masashi Kitamura, Takeshi Yatsuo, Hiroshi Tazaki, Shigeru Kakugawa, Noriaki Hino, Hirotaka Takeshima
Publikováno v:
IEEE Transactions on Appiled Superconductivity. 14:1639-1642
We have developed a new magnet for open high field (0.7 T) MRI systems. Since MRI systems are installed in hospital sites, it is important to reduce stray magnetic fields of the magnets. We studied passive, active and hybrid shielding methods and com
Autor:
Hirotaka Takeshima, Takeshi Yatsuo, Hiroshi Tazaki, Shigeru Kakugawa, Akiyoshi Komura, Noriaki Hino, Masashi Kitamura
Publikováno v:
IEEE Transactions on Appiled Superconductivity. 14:1624-1627
We have developed a new magnet for open high field (0.7 T) MRI systems. In order to homogenize magnetic fields in the field of view, an optimization method to determine initial configurations of large correction iron pieces was developed. In our meth
Autor:
Noriaki Hino, Akiyoshi Komura, Masashi Kitamura, Takao Honmei, Hirotaka Takeshima, Shigeru Kakugawa
Publikováno v:
IEEE Transactions on Appiled Superconductivity. 9:366-369
Optimal coil configurations in a split-type superconducting MRI magnet have been investigated, and the feasibility of the compact and high performance magnet is presented. A highly homogeneous magnetic field of about 10 ppm/50 cm diameter spherical v
Publikováno v:
ChemInform. 44
The treatment of a variety of hydrosilanes, each incorporating a benzylic C(sp(3))-H bond, with a rhodium catalyst resulted in intramolecular dehydrogenative silylation. This silylation reaction was found to occur at typically unreactive C(sp(3))-H b
Autor:
Naoko Tsuru, Hiroaki Takahashi, Hirotaka Takeshima, Tomomi Kawakami, Akira Ikeda, Shin-ichi Hagimori, Michiro Kawakami, Isao Uno, Kazuo Makimoto, Yasuo Uesugi
Publikováno v:
Practica Oto-Rhino-Laryngologica. 87:1229-1237
Autor:
Isao Uno, Hirotaka Takeshima, Hiroaki Takahashi, Kohhei Wada, Toshiji Fujisawa, Takeyo Watanabe, Kenshi Omori, Yuzo Yamamoto, Tatsuya Sadaoka, Tetsuro Saka, Ibuki Hayashi, Noriya Kakitsube, Isao Inuoe, Ryusaburo Nonaka, Atsushi Sakakura, Sumiko Nakakouji, Kazuo Makimoto, Takao Fujita
Publikováno v:
Practica Oto-Rhino-Laryngologica. 87:985-995