Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Hiroshi Tsuneishi"'
Publikováno v:
Journal of the American Chemical Society. 119:472-478
Enantiodifferentiating photoisomerizations of (Z,Z)-1,3-cyclooctadiene (1ZZ) to the chiral E,Z-isomer 1EZ were performed at varying temperatures in the presence of some benzenepoly-, naphthalene(di...
Autor:
Kazuharu Nakagawa, Yoshihisa Inoue, Hiroshi Tsuneishi, Tadao Hakushi, Lin-Hui Tong, Akira Tai, Kaoru Matsumoto, Satoru Kosaka
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 71:61-64
An inclusion complex of (Z)-cyclooctene (1Z) with β-cyclodextrin (β-CD) was synthesized in aqueous solution and shown to be a stoichiometric 1:1 complex by thermogravimetry-differential thermal analysis (TG-DTA) and gas chromatography (GC) analysis
Publikováno v:
ChemInform. 24
Effects of methylation at C(1) of cyclooctene on the ground-state structure, potential energy surfaces, and photochemical behaviour in the singlet and triplet manifolds have been investigated. Molecular mechanics calculations using the MM2 force fiel
Publikováno v:
ChemInform. 28
Enantiodifferentiating photoisomerizations of (Z,Z)-1,3-cyclooctadiene (1ZZ) to the chiral E,Z-isomer 1EZ were performed at varying temperatures in the presence of some benzenepoly-, naphthalene(di...
Publikováno v:
ChemInform. 28
A newly developed polarizing undulator installed in a storage ring was employed for the first time as a source of circularly polarized synchrotron radiation in the vacuum ultraviolet to effect enantiodifferentiating direct photoisomerization of (E)-c
Autor:
Hiroshi Tsuneishi, Tadao Hakushi, Yoshihisa Inoue, Akira Tai, Shin’ichi Umemoto, Hitoshi Shimizu, Takashi Sugimura
Publikováno v:
ChemInform. 29
Photolysis of a tethered cyclooctene (E)-4, in which the sensitizer benzoate is connected to the olefin moiety through a chiral 2,4-pentanediol tether, afforded the Z/E ratios up to 0.8 and the diastereomeric excess of 33% at −65 °C, while the ter
Autor:
Tadao Hakushi, Hitoshi Shimizu, Yoshihisa Inoue, Takashi Sugimura, Hiroshi Tsuneishi, Shin’ichi Umemoto, Akira Tai
Publikováno v:
Chemistry Letters. 27:323-324
Photolysis of a tethered cyclooctene (E)-4, in which the sensitizer benzoate is connected to the olefin moiety through a chiral 2,4-pentanediol tether, afforded the Z/E ratios up to 0.8 and the diastereomeric excess of 33% at −65 °C, while the ter
Autor:
Yoshihisa Inoue, Keiko Yamamoto, Tadao Hakushi, Akira Tai, Fang Dong, Lin-Hui Tong, Hiroshi Tsuneishi
Publikováno v:
Journal of the American Chemical Society. 117:11033-11034
Publikováno v:
Chemical Communications. :2627
A newly developed polarizing undulator installed in a storage ring was employed for the first time as a source of circularly polarized synchrotron radiation in the vacuum ultraviolet to effect enantiodifferentiating direct photoisomerization of (E)-c
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1601
Photosensitized enantiodifferentiating geometrical isomerizations of (Z)-cyclooctene (1Z), producing the chiral (E)-isomer (1E), were performed in triplet, as well as singlet, states in order to clarify the effects of spin multiplicity upon the produ