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pro vyhledávání: '"Hiroki Chikamori"'
Autor:
Hiroki Chikamori, Toshiro Takao
Publikováno v:
Organometallics. 38:2705-2709
A μ3-methylidyne complex of ruthenium, [(Cp*Ru)3(μ3-CH)(μ-H)2(μ3-S)] (3; Cp* = (C5Me5)Ru), was synthesized by the reaction of [{Cp*Ru(μ-H)}3(μ3-H)2] (1) with thioanisole. Complex 3 isomerized to a ...
Publikováno v:
Organometallics. 39(No. 2):527-535
A triruthenium complex containing μ3-η2(||)-benzyne and μ3-sulfido ligands, [(Cp*Ru)3(μ3-S){μ3-η2(||)-C6H4}(μ-H)] (2), was synthesized by the reaction of [(Cp*Ru)3(μ3-S)(μ-H)3] (1) with benzene. Although 2 was stable toward oxygen and water,
Autor:
Hiroki Chikamori, Yutaka Ito, Ryuichi Shimogawa, Asuka Koizumi, Hiroharu Suzuki, Junko Fujimoto, Hajime Kameo, Toshiro Takao
Publikováno v:
Dalton Transactions. 46:5631-5643
Dicationic tetranuclear ruthenium octahydride [(Cp*Ru)4H8]2+ (5) with tetrahedral geometry was obtained by reaction of dinuclear ruthenium tetrahydride (Cp*Ru)2(μ-H)4 (1) with an excess of Bronsted acids, such as HBF4·OEt2, in toluene. Monocationic