Zobrazeno 1 - 10
of 228
pro vyhledávání: '"Hirohisa Ohmiya"'
Autor:
Kenji Ota, Kazunori Nagao, Dai Hata, Haruki Sugiyama, Yasutomo Segawa, Ryosuke Tokunoh, Tomohiro Seki, Naoya Miyamoto, Yusuke Sasaki, Hirohisa Ohmiya
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-9 (2023)
Abstract Chemical modification of nucleotides can improve the metabolic stability and target specificity of oligonucleotide therapeutics, and alkylphosphonates have been employed as charge-neutral replacements for naturally-occurring phosphodiester b
Externí odkaz:
https://doaj.org/article/1f49951f219d47978c13c5c914215477
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-7 (2022)
Although electrochemical semipinacol rearrangements have been reported, a complementary photochemical route has yet to be developed. Here the authors report an organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover.
Externí odkaz:
https://doaj.org/article/0e56a20c12094e7ba9c5b75ea389e772
Autor:
Yuki Matsuki, Nagisa Ohnishi, Yuki Kakeno, Shunsuke Takemoto, Takuya Ishii, Kazunori Nagao, Hirohisa Ohmiya
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
Use of aryl halides as coupling precursors typically occurs through transition metal catalysis and/or photoredox chemistry, which requires some combination of light, metals, and oxidants or reductants. Here, the authors show a method to generate aryl
Externí odkaz:
https://doaj.org/article/f36b6c5bc0004213ae418b24ec57fb2a
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 185-189 (2020)
The allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions is described. The synergistic palladium/copper-catalyzed reaction of aromatic aldehydes, allylic carbonates, and a silylboronate produces the corresponding homoallylic alcoh
Externí odkaz:
https://doaj.org/article/0e49de485ed143e8be821545e81f2ca4
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 11, Iss 1, Pp 2444-2450 (2015)
A copper-catalyzed conjugate addition of alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) to alkynoates to form β-disubstituted acrylates is reported. The addition occurred in a formal syn-hydroalkylation mode. T
Externí odkaz:
https://doaj.org/article/6748c8dec1ca4b3c90585b4b8dccb952
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 951-959 (2011)
The gold-catalyzed, seven-membered ring forming, intramolecular hydroamination of alkynic sulfonamides has been investigated. The protocol, with a semihollow-shaped triethynylphosphine as a ligand for gold, allowed the synthesis of a variety of azepi
Externí odkaz:
https://doaj.org/article/fb5a21883321419f8661691d122ddaf5
Autor:
Rikako Nakamura, Takeru Yamazaki, Yui Kondo, Miho Tsukada, Yusuke Miyamoto, Nozomi Arakawa, Yuto Sumida, Taketoshi Kiya, Satoshi Arai, Hirohisa Ohmiya
Publikováno v:
Journal of the American Chemical Society. 145:10651-10658
Autor:
Yunosuke Takekawa, Taiga Kodo, Kazunori Nagao, Hiroyuki Kakei, Kohei Takeuchi, Yusuke Sasaki, Hirohisa Ohmiya
Publikováno v:
Chemistry Letters. 52:41-43
Publikováno v:
Bulletin of the Chemical Society of Japan. 95:1001-1005
Publikováno v:
ACS Catalysis. 12:7804-7810