Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Hiro Teramoto"'
Publikováno v:
Results in Chemistry, Vol 4, Iss , Pp 100364- (2022)
Asymmetric silane reduction of ketones catalyzed by a system comprising a chiral azolium salt 1 and [Ir(cod)2]BF4 (2) in the presence of a base in methanol was achieved at room temperature within 2 h. Implementing a “pre-mixing” experimental proc
Externí odkaz:
https://doaj.org/article/0fd2ae2b38d24fe3bab6c96356f96eb6
Autor:
Hiro Teramoto, Satoshi Sakaguchi
Publikováno v:
Journal of Organometallic Chemistry. 875:52-58
This study aims to propose a simple procedure for the development of enantioselective hydrosilylation of a ketone using catalytic amounts of [Ir(cod)2]BF4 and chiral azolium salt. Previously, catalytic asymmetric hydrosilylation reactions have used w
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::af662b91424f6a769dff1dfdf80782ee
https://doi.org/10.1016/j.jorganchem.2018.09.001
https://doi.org/10.1016/j.jorganchem.2018.09.001
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 421:138-145
Enantioselective reduction of ketones with (EtO) 2 MeSiH catalyzed by an in-situ generated N -heterocyclic carbene (NHC) Ir complex at room temperature has been developed. A series of benzimidazolium salts were synthesized and screened in the asymmet
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::82e02ad70e1ddeb62d0a1e71f83e64a6
https://doi.org/10.1016/j.molcata.2016.05.020
https://doi.org/10.1016/j.molcata.2016.05.020