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Publikováno v:
J. Chem. Soc. A. :3119-3122
The ionization constants of carboxylic acids of the type, PhnMe3 –nMCO2H (M = C, Si, and Ge) have been determined in 45 and 76%(w/w) ethanol–water at 25°. In all cases the triorganosilane- and triorganogermane-carboxylic acids are more acidic th