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Synthetic Studies toward Aplysiasecosterol A: Concise Synthesis of the Tricyclic Core and Its Reactions for Introduction of the D Ring Fragment

Autor: Hikaru Tano, Takayuki Ohyoshi, Hideo Kigoshi

Publikováno v: Bulletin of the Chemical Society of Japan. 94:1179-1184

Aplysiasecosterol A, a 9,11-secosteroid, has a unique tricyclic γ-diketone skeleton including a hemiacetal. The concise and efficient synthesis of the tricyclic core was developed by using pseudo-d...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4f666b7fc4b697d2323bdd90f5b25eda
https://doi.org/10.1246/bcsj.20200401

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Synthetic studies toward aplysiasecosterol A: Construction of the novel tricyclic core

Autor: Hideo Kigoshi, Hikaru Tano, Kei Akemoto, Takayuki Ohyoshi

Publikováno v: Tetrahedron Letters. 58:3327-3329

Aplysiasecosterol A, a 9,11-secosterol compound, has a unique tricyclic γ-diketone skeleton including a hemiacetal. The novel tricyclic core of aplysiasecosterol A is constructed by using intramolecular radical cyclization as a key step.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6e407220219037aa9212b99babc102f5
https://doi.org/10.1016/j.tetlet.2017.07.036

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Akademický článek

Synthetic Studies toward Aplysiasecosterol A: Concise Synthesis of the Tricyclic Core and Its Reactions for Introduction of the D Ring Fragment.

Autor: Takayuki Ohyoshi, Hikaru Tano, Hideo Kigoshi

Publikováno v: Bulletin of the Chemical Society of Japan; Apr2021, Vol. 94 Issue 4, p1179-1184, 6p

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