Hydrogenative Cycloisomerization and Sigmatropic Rearrangement Reactions of Cationic Ruthenium Carbenes Formed by Catalytic Alkyne gem‐Hydrogenation.

Autor: Biberger, Tobias¹ (AUTHOR), Hess, Stephan N.¹ (AUTHOR), Leutzsch, Markus¹ (AUTHOR), Fürstner, Alois¹ (AUTHOR) fuerstner@kofo.mpg.de

Publikováno v: Angewandte Chemie. 2/14/2022, Vol. 134 Issue 8, p1-6. 6p.

Enantioselective synthesis of

Autor: Sun, Alexander W., Hess, Stephan N., Stoltz, Brian M.

Publikováno v: Chemical Science

An enantioselective synthesis of diverse N4-Boc-protected α,α-disubstituted piperazin-2-ones and tetrahydropyrimidin-2-ones using the palladiumcatalyzed decarboxylative allylic alkylation reaction has been achieved.
An enantioselective synthes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid_dedup__::068ff8d5dd3b5a570d2c13102eef7e96
https://pubmed.ncbi.nlm.nih.gov/30774872

Enantioselective synthesis of gem -disubstituted N -Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation.

Autor: Sun AW; Warren and Katherine Schlinger Laboratory for Chemistry and Chemical Engineering , Division of Chemistry and Chemical Engineering , California Institute of Technology , Pasadena , California 91125 , USA . Email: stoltz@caltech.edu., Hess SN; Warren and Katherine Schlinger Laboratory for Chemistry and Chemical Engineering , Division of Chemistry and Chemical Engineering , California Institute of Technology , Pasadena , California 91125 , USA . Email: stoltz@caltech.edu., Stoltz BM; Warren and Katherine Schlinger Laboratory for Chemistry and Chemical Engineering , Division of Chemistry and Chemical Engineering , California Institute of Technology , Pasadena , California 91125 , USA . Email: stoltz@caltech.edu.

Publikováno v: Chemical science [Chem Sci] 2018 Oct 31; Vol. 10 (3), pp. 788-792. Date of Electronic Publication: 2018 Oct 31 (Print Publication: 2019).