Zobrazeno 1 - 10
of 121
pro vyhledávání: '"Herman Van Halbeek"'
Autor:
Rolland M. Waters, Herman van Halbeek, I.L. Honigberg, Alva D. Mitchell, J. D. Warthen, Walter F. Schmidt
Publikováno v:
International Journal of Peptide and Protein Research. 41:467-475
Synthesized beta 1- and beta 2-pentapeptide sequences corresponding to published adrenoceptor transmembrane activation site subtypes were investigated in vitro for selectivity in association for drug ligands of known selectivity. Both nuclear magneti
Publikováno v:
Angewandte Chemie. 120:6162-6165
Publikováno v:
Angewandte Chemie International Edition. 47:6073-6076
Monomeric, early-transition-metal imide complexes [M=NR], which mediate numerous catalytic and stoichiometric nitrogen-transfer reactions,[1a] can be prepared by α abstraction and extrusion of a good leaving group (e.g. alkane or amine) from a metal
Autor:
Johanna H. G. M. Mutsaers, Johannis P. Kamerling, Johannes F.G. Vliegenthart, Herman Van Halbeek
Publikováno v:
European Journal of Biochemistry. 147:569-574
Prostaglandin endoperoxide synthase was isolated from sheep seminal vesicles. Sugar analysis of the glycoprotein revealed the presence of mannose and N-acetylglucosamine only. The carbohydrate moiety was released from the polypeptide backbone by hydr
Publikováno v:
Carbohydrate Research. 342:2014-2030
In this work, we describe the synthesis and NMR characterization of four mono- and four dideoxygenated analogs of alpha,alpha-D-trehalose. The symmetrical (2,2'-, 3,3'-, 4,4'- and 6,6'-) dideoxy analogs were obtained via selective protection and subs
Publikováno v:
Journal of the American Chemical Society. 127:2686-2695
The Staudinger ligation of azides and phosphines has found widespread use in the field of chemical biology, but the mechanism of the transformation has not been characterized in detail. In this work, we undertook a mechanistic study of the Staudinger
Publikováno v:
Angewandte Chemie. 116:6526-6529
Publikováno v:
Journal of Neurochemistry. 65:2344-2349
Our studies of bovine brain neutral glycosphingolipids (Ngsls) have revealed the presence of several short-chain (containing -CHO 1-4) and previously uncharacterized long-chain (-CHO > 4-5) Ngsls. We reported the structural characterization of brain
Publikováno v:
Journal of Biological Chemistry. 277:17502-17510
The glycosidic linkage of sialic acids is much more sensitive to acid hydrolysis than those of other monosaccharides in vertebrates. The commonest sialic acids in nature are neuraminic acid (Neu)-based and are typically N-acylated at the C5 position.
Autor:
Herman van Halbeek, Bryan E. F. Tiedemann, Rudi Nunlist, Kenneth N. Raymond, Michael D. Pluth
Publikováno v:
Inorganic Chemistry. 47:1411-1413
The diffusion coefficient of the self-assembled supramolecular cluster [Ga4L6]12− depends on the cationic counterions in solution. Diffusion coefficients were determined using the pulsed-gradient spin–echo 1H NMR method and fit using nonlinear le