Zobrazeno 1 - 10
of 42
pro vyhledávání: '"Heribert A. Graetsch"'
Publikováno v:
Chemistry of Materials. 32:1844-1853
Tetragonal tungsten bronze (TTB), with a flexible chemical framework, is an important class of ferroelectric oxide that hosts both the frequency-independent ferroelectric behavior as well as the br...
Autor:
Heribert A. Graetsch
Publikováno v:
Journal of Chemical Crystallography. 48:177-184
Interatomic distance considerations and site occupancy refinements indicate that Zn2+ is exclusively located on tetrahedral sites in both Z and X-type hexagonal ferrites. Zinc is more strongly enriched in four layer thick spinel blocks of X-type hexa
Autor:
Heribert A. Graetsch
Publikováno v:
Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials. 73:820-826
Quenching of Sr0.52Ba0.48Nb2O6(SBN52) from temperatures above 700°C causes small modifications in the strontium distribution over the large cation sites (Me1 and Me2), changed off-centre shifts of the Nb atoms and slightly increased modulation ampli
Autor:
Heribert A. Graetsch
Publikováno v:
Journal of Solid State Chemistry. 246:167-175
The amplitudes of the positional, occupational and adp modulations of sbn mixed crystals are strongly enhanced for high strontium contents. The increase of structural modulations is accompanied by reduced spontaneous electric polarization largely due
Autor:
Heribert A, Graetsch
Publikováno v:
Acta crystallographica Section B, Structural science, crystal engineering and materials. 73(Pt 5)
Quenching of Sr
Publikováno v:
Journal of Solid State Chemistry. 196:255-266
The incommensurately modulated crystal structure of relaxor ferroelectric CBN28 was refined at elevated temperatures up to 330 °C in the 3+2 dimensional superspace group P 4 bm ( αα 1/2,− αα 1/2). The structural modulations mainly consisting o
Autor:
Heribert A. Graetsch
Publikováno v:
Neues Jahrbuch für Mineralogie - Abhandlungen. 188:111-117
Autor:
Ian S. Buick, Werner Schreyer, Birgit Pöter, Christopher J. Carson, Edward S. Grew, Martin G. Yates, Günter Werding, Geoffrey L. Clarke, Heinz-Jürgen Bernhardt, Heribert A. Graetsch
Publikováno v:
American Mineralogist. 93:283-299
Boralsilite, the only natural anhydrous ternary B 2 O 3 -Al 2 O 3 -SiO 2 (BAS) phase, has been synthesized from BASH gels with Al/Si ratios of 8:1 and 4:1 but variable B 2 O 3 and H 2 O contents at 700–800 °C, 1–4 kbar, close to the conditions e
Autor:
Heribert A. Graetsch
Publikováno v:
Zeitschrift für Kristallographie. 222:226-233
Similar to silica tridymite, the corresponding AlPO4 analogue shows a sequence of displacive phase transitions at elevated temperatures. The transformation temperatures are lower than for SiO2 tridymite. The incommensurate structure of the tridymite
Autor:
Heribert A. Graetsch, Michela Brunelli
Publikováno v:
Zeitschrift für Kristallographie - Crystalline Materials. 220:606-613
The crystal structure of the incommensurate modification of SiO2 tridymite existing between 150 and 200 °C was refined in the 3 + 1 dimensional superspace group P21(α β 0) from synchrotron powder diffraction data. The modulation consists of rotati