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pro vyhledávání: '"Herbert Naarmann"'
Publikováno v:
Electroresponsive Molecular and Polymeric Systems ISBN: 9781003210047
Electroresponsive Molecular and Polymeric Systems
Electroresponsive Molecular and Polymeric Systems
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e369b63b6839660322c6d5e5d10e946b
https://doi.org/10.1201/9781003210047-1
https://doi.org/10.1201/9781003210047-1
Publikováno v:
Annales de Chimie Science des Matériaux. 29:55-61
We report the synthesis and electropolymerization of 3-(3’-thienyl-5’-phenylverdazyl)thiophene with hexafluorophosphate as the counter anion, that gives solid materials with a high concentration of radical spins. A portion of the magnetic moments
Publikováno v:
Tetrahedron. 51:2533-2542
Various substituted benzo-mono-, bis-, and tris-1,2,3-trithioles were synthesized by reaction of the corresponding thiolates with sulfur dichloride. Benzo-bis(trithiolo)pentathiepin was isolated as a by-product. These trithioles form with cyanide dib
Publikováno v:
Journal of Physics: Condensed Matter. 6:L511-L515
Electropolymerization of 1, 3-dithienyl-5-phenylverdazyl with hexafluorophosphate as the counter anion gives solid materials with a high concentration of radical spins. A portion of the magnetic moments show magnetic order with spontaneous magnetizat
Autor:
Stephen J. van Eyk, Herbert Naarmann
Publikováno v:
Synthetic Metals. 58:233-242
A model of the proposed macrocyclic polypyrrole has been synthesized and in discussed. Also proposed is an interesting form of polypyrrole borne from these studies with a fullerene-like structure. A possible synthetic method to it is discussed.
Autor:
Herbert Naarmann, N. Walker, W. Dyakonow, Elmar Dormann, Hubert Winter, A. Lang, B. Gotschy, B. Pilawa
Publikováno v:
Synthetic Metals. 56:3273-3278
The magnetic properties of 1,3,5,6-tetraphenyl-verdazyl and related verdazyls were characterized by static magnetic susceptibility measurements (1.8K ≤ T ≤ 300K, H ≤ 55 kOe), ESR (10 GHz, solid and solution) and proton NMR (360 MHz, dilute solu
Publikováno v:
Synthetic Metals. 53:379-398
The 1H NMR spectra of verdazyls displaying magnetic interactions are examined. This is the first occasion on which the 1H NMR spectra have been reported for these particular materials and the synthesis of a number of new verdazyls is also reported. T
Autor:
Francisco Martinez, Herbert Naarmann
Publikováno v:
ChemInform. 23
The synthesis of new 5-substituted isatins with 2-thienyl, 3-thienyl, 2,2′-bithien-5-yl and phenyl substituents is described. The compounds were prepared via the palladium-catalysed cross-coupling reaction of 5-bromoisatin with 2-thiophene, 3-thiop
Publikováno v:
Polyhedron. 11:1099-1107
In the reaction of bis(trimethylsilyl)carbodiimide ( 1 ) with excess PF 2 Cl only the monosubstituted carbodiimide 2a was obtained. The carbodiimide structure is suggested by 15 N and 29 Si NMR spectra. Two equivalents of 2a were found to react with
Publikováno v:
Synthetic Metals. 42:1567-1570
Gas phase polymerization of simple allenes and alkynes at 460°C provides stable black films or coatings which become electrically conducting when doped with iodine or various Lewis acids. The range of application of this novel route to conducting po