Zobrazeno 1 - 10
of 34
pro vyhledávání: '"Herbarumin III"'
Publikováno v:
Helvetica Chimica Acta. 93:1634-1640
The total synthesis of herbarumin III (1) was achieved via an alkynide ion addition onto a chiral aldehyde and LiAlH4/LiI reduction as key steps (Scheme 2).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fad823213563e8702f3824e69feb3fec
https://doi.org/10.1002/hlca.200900427
https://doi.org/10.1002/hlca.200900427
Autor:
Pradeep Kumar, P. Gupta
Publikováno v:
Synlett. 2009:1367-1382
A variety of racemic epoxides mainly derived from terminal olefins,such as aliphatic epoxides, multifunctionalized epoxides and amine-substitutedepoxides, have been successfully resolved into the enantiomericallypure epoxides and diols using -Jacobse
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9205b28e42cca7028f0d207cf64b1a2a
https://doi.org/10.1055/s-0029-1217171
https://doi.org/10.1055/s-0029-1217171
Publikováno v:
Synthesis. 2008:3945-3950
The total synthesis of herbarumin III is described, proving the versatility of the Prins cyclization in the synthesis of natural products. The approach is convergent and highly stereoselective. Ring-closing metathesis and alkene-rearrangement reactio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bf403a348a15e274c330d2d2c3f5dbd3
https://doi.org/10.1055/s-0028-1083249
https://doi.org/10.1055/s-0028-1083249
Publikováno v:
Synthesis. 2008:1938-1942
A stereoselective total synthesis of the phytotoxic com- pound herbarumin III has been achieved by utilizing Crimmins's aldol approach, 1,3-syn asymmetric reduction, and an olefin meta- thesis reaction as the key steps.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::00ec3bbfa57c6e9271a437bc4b5a5c01
https://doi.org/10.1055/s-2008-1067089
https://doi.org/10.1055/s-2008-1067089
Publikováno v:
ARKIVOC, Vol 2005, Iss 3, Pp 237-257 (2005)
Total synthesis of naturally occurring microcarpalide and herbarumin III are described. The ring- closing metathesis (RCM) approach to coin the medium sized rings present in their molecular structures form the basic premise of this investigation.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9193eb621e24b7b6f6312c7c622ffd3c
https://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/ark.5550190.0006.326
https://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/ark.5550190.0006.326
Publikováno v:
European Journal of Chemistry. 3:337-339
A formal stereoselective synthesis of Herbarumin III has been accomplished starting from butanal involving Maruoka asymmetric allylation, diastereoselective iodine-induced electrophilic cyclization and conversion of iodocarbonate into syn -epoxy alco
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bcaa7a70403e746e815cef5cc1e54369
https://doi.org/10.5155/eurjchem.3.3.337-339.609
https://doi.org/10.5155/eurjchem.3.3.337-339.609
Publikováno v:
Chinese Chemical Letters. 18:255-257
The asymmetric total synthesis of herbarumin III 3, a naturally occurred phytotoxin, along with 8-epi-herbarumin III 22, was succeeded in 12 steps from n-butyraldehyde based on Brown's asymmetric allylation, taking modified Julia olefination and Yama
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0b47913d20275b145c50a16d379977eb
https://doi.org/10.1016/j.cclet.2007.01.035
https://doi.org/10.1016/j.cclet.2007.01.035
Autor:
Samik Nanda
Publikováno v:
Tetrahedron Letters. 46:3661-3663
Asymmetric total synthesis of phytotoxic nonenolide herbarumin III was accomplished by a chemoenzymatic approach. The main highlight of the synthesis was to fix the hydroxyl stereocenters (C7 and C9) by lipase catalyzed irreversible transesterificati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e8802fc678d2c6d3bec577c4ed94c5ee
https://doi.org/10.1016/j.tetlet.2005.03.139
https://doi.org/10.1016/j.tetlet.2005.03.139
Publikováno v:
ChemInform. 42
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c6e386ee86d8012d13e720f0c935dc8f
https://doi.org/10.1002/chin.201150190
https://doi.org/10.1002/chin.201150190
Publikováno v:
ChemInform. 35
An asymmetric 10-step total synthesis of herbarumin III in 24% overall yield is described using ring-closing metathesis as the key step.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a59f967c5606e62493e58d02fce734b2
https://doi.org/10.1002/chin.200437216
https://doi.org/10.1002/chin.200437216