Reaction of nido-7,8-C2B9H13 with Dicobalt Octacarbonyl: Crystal Structures of the Complexes [Co2(CO)2(η5-7,8-C2B9H11)2], [Co2(CO)(PMe2Ph)(η5-7,8-C2B9H11)2], and [CoCl(PMe2Ph)2(η5-7,8-C2B9H11)]

Autor: J. C. Jeffery, Paul A. Jelliss, Eric L. Sappenfield, Donald F. Mullica, Hendershot Sl, Fga Stone

Publikováno v: Inorganic Chemistry. 35:6561-6570

The compounds [Co2(CO)8] and nido-7,8-C2B9H13 react in CH2Cl2 to give a complex mixture of products consisting primarily of two isomers of the dicobalt species [Co2(CO)2(η5-7,8-C2B9H11)2] (1), together with small amounts of a mononuclear cobalt comp

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::33248bd8085a7e05b0a7391e9c7fb2ea
https://doi.org/10.1021/ic960560s

Reaction of nido-7,8-C(2)B(9)H(13) with Dicobalt Octacarbonyl: Crystal Structures of the Complexes [Co(2)(CO)(2)(eta(5)-7,8-C(2)B(9)H(11))(2)], [Co(2)(CO)(PMe(2)Ph)(eta(5)-7,8-C(2)B(9)H(11))(2)], and [CoCl(PMe(2)Ph)(2)(eta(5)-7,8-C(2)B(9)H(11))].

Autor: Hendershot SL; Department of Chemistry, Baylor University, Waco, Texas 76798-7348, and School of Chemistry, University of Bristol, Bristol BS8 1TS, U.K., Jeffery JC, Jelliss PA, Mullica DF, Sappenfield EL, Stone FG

Publikováno v: Inorganic chemistry [Inorg Chem] 1996 Oct 23; Vol. 35 (22), pp. 6561-6570.