Zobrazeno 1 - 10
of 22
pro vyhledávání: '"Helmut Fric"'
Publikováno v:
Food Control. 50:548-553
Food packaging materials fundamentally contribute to food quality and safety, as they protect the packaged food against external influences. In this context, the determination of the hygiene status of the packaging material is of great importance. Ho
Autor:
Maria Bendova, Stefan O. Baumann, Claudia Visinescu, Michael Puchberger, Helmut Fric, Ulrich S. Schubert
Publikováno v:
European Journal of Inorganic Chemistry. 2009:3333-3340
Crystalline oximate derivatives of titanium alkoxides [Ti(OR)2(ON=CR′R″)2]2 were obtained when Ti(OR)4 (R = iPr, Et) was treated with various oximes (cyclopentanone oxime, cyclohexanone oxime, acetoxime, ethyl methyl ketoxime or 2,4-pentandione d
Publikováno v:
European Journal of Inorganic Chemistry. 2008:1452-1461
The structures of Ti2(OiPr)6(OCHMeCH2NH2)2 and Ti 2 (OiPr) 6 -(OCH 2 CHMeNH 2 ) 2 , obtained by reaction of Ti(OiPr) 4 with the corresponding amino alcohols, were investigated to elucidate the structural influence of the organic substituents at the a
Publikováno v:
Monatshefte für Chemie - Chemical Monthly. 138:529-539
Metal-alkoxides containing polymerizable groups are regularly used as precursors for inorganic–organic hybrid materials applying the combination of the sol–gel process and organic polymerizations. Here we report the synthesis of acetoacetoxy deri
Autor:
Helmut Fric, Ulrich S. Schubert
Publikováno v:
Zeitschrift für Naturforschung B. 62:487-490
The imide derivatives Li4Ti4O2(NR)2(OiPr)12 (R = CH2C6H5, C6H11, C4H9) were obtained either by reaction of the amine adduct Ti2(OiPr)8(H2NR)2 with lithium diiso- propylamide or butyllithium, or when the primary amine was first reacted with the base a
Publikováno v:
European Journal of Inorganic Chemistry, 2007(3), 376-383. Wiley-VCH Verlag
The reaction of bis(2-aminoethyl)amine with M(OiPr) 4 (M = Ti, Zr) affords the chain-like coordination polymers [M 2 (OiPr) B -(H 2 NCH 2 CH 2 NHCH 2 CH 2 NH 2 )] ∞ , where only the NH 2 groups of the amine are coordinated to the M 2 (OiPr) 8 units
Autor:
Michael Puchberger, Silvia Gross, Helmut Fric, Ulrich S. Schubert, Myhedin Jupa, Franz René Kogler, Guido Kickelbick
Publikováno v:
European Journal of Inorganic Chemistry. 2006:3283-3293
Upon reaction of zirconium alkoxides, Zr(OR)4, with carboxylic acids, the clusters Zr6O4(OH)4(OOCR)12 (Zr6) or [Zr6O4(OH)4(OOCR)12]2 (Zr12) were obtained, depending on the employed carboxylic acid. The structures of Zr12 clusters with acetate, propio
Publikováno v:
Journal of Sol-Gel Science and Technology. 40:155-162
The structural chemistry of crystalline adducts M2(OR)8(amine)2 (M = Ti: OR = OiPr, amine = NH2CH2Ph, NH2Bu; M = Ti: OR = OEt, amine = piperidine; M = Zr: OR = OiPr, amine = NH2CH2Ph, NH2C6H11) is discussed. The adducts were obtained by reaction of T
Publikováno v:
Monatshefte für Chemie - Chemical Monthly. 137:1-6
The yttrium carboxylates Y(methacrylate)3 and Y(acetate)3·0.5 H2O were prepared by reaction of Y(OCH2CH2OMe)3 with methacrylic or acetic acid and characterized by X-ray structure analyses. Both carboxylates have chain structures with both bridging a
Autor:
Helmut Fric, Ulrike Bauer, Michael Puchberger, Ulrich S. Schubert, Viktoria Torma, Wolfgang Rupp
Publikováno v:
ResearcherID
Bidentate ligands are potentially useful to modify metal alkoxides precursors for sol-gel processing. However, anionic bidentate ligands are needed to get a strong coordination, while diamines as neutral bidentate ligand form coordination polymers [T