Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Helena M. Carapuça"'
Publikováno v:
Thin Solid Films. 518:5881-5888
Ultrathin multilayer films containing metal-substituted polyoxometalates, [PW11FeIII(H2O)O39]4− (PW11Fe) or [SiW11FeIII(H2O)O39]5− (SiW11Fe), and poly(ethylenimine) (PEI) were prepared by the electrostatic layer-by-layer self-assembly method on a
Autor:
Ana M. V. Cavaleiro, Susana Simões, Christopher M.A. Brett, Helena M. Carapuça, Diana M. Fernandes
Publikováno v:
Journal of Electroanalytical Chemistry. 639:83-87
Novel poly(hexylmethacrylate) carbon composite electrodes have been prepared from graphite powder and poly(hexylmethacrylate) binder, and modified with Keggin-type polyoxotungstate anions in the form of tetra-n-butylammonium (TBA) hybrid salts. The s
Publikováno v:
Journal of Electroanalytical Chemistry. 626:192-196
In this work, polyelectrolyte coatings assembled on glassy carbon/thin mercury film electrodes, as an adsorbed layer of poly(sodium 4-styrenesulfonate) (PSS), were studied. The goal was to search for the best conditions for the production of stable P
Publikováno v:
Electrochimica Acta. 53:6580-6588
Novel glassy carbon modified electrodes were functionalised with tetra- n -butylammonium (TBA) hybrid salts of several α-Keggin-type polyoxosilicotungstate anions. The salts were immobilized via a one-step deposition of micrometer thick coatings by
Publikováno v:
Journal of Electroanalytical Chemistry. 610:37-45
In this work, the performance and applicability of the thin mercury film electrode (TMFE) in the heavy metal speciation, by stripping chronopotentiometry (SCP), were exploited. The TMFE thickness was optimized and a 7.6 nm mercury film was selected.
Publikováno v:
Electrochimica Acta. 52:1182-1190
Glassy carbon electrodes coated with adsorbed single layers of the cationic polyelectrolyte poly(allylamine hydrochloride), PAH, were produced by solvent evaporation for subsequent development of PAH modified thin mercury film electrodes (PAH/TMFE).
Autor:
Helena M. Carapuça, Luciana S. Rocha
Publikováno v:
Bioelectrochemistry. 69:258-266
The incorporation/exclusion features of dopamine (DA), ascorbic acid (AA) and uric acid (UA) are evaluated for Nafion (NA)-coated glassy carbon electrodes (GCE) of different thicknesses. The ion-exchange partition of DA(+) between the NA film and the
Publikováno v:
Langmuir. 22:8241-8247
This work aimed to produce improved polymer coatings for the modification of thin mercury film electrodes (TMFEs). The goal is to obtain sensitive, reproducible, mechanically stable and antifouling devices suitable for the determination of trace meta
Publikováno v:
Talanta. 68:1655-1662
The present work describes the preparation, optimization and characterization of mixed polyelectrolyte coatings of poly-l-lysine (PLL) and poly(sodium 4-styrenesulfonate) (PSS) for the modification of thin mercury film electrodes (MFEs). The novel-mo
Publikováno v:
Talanta
Talanta, Elsevier, 2005, 66, pp.844-857. ⟨10.1016/j.talanta.2004.12.036⟩
Talanta, Elsevier, 2005, 66, pp.844-857. ⟨10.1016/j.talanta.2004.12.036⟩
Studies of trace metal mobilization in sediments are generally performed using sequential extraction schemes at equilibrium. In the present work, a kinetic fractionation of trace metals in sediments has been developed to assess that information. The