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pro vyhledávání: '"Helen A. A. Dickson"'
Autor:
Helen A. A. Dickson, Jonathan P. H. Charmant, Selby A. R. Knox, A. Guy Orpen, Nigel J. Grist, Josep M. Viñas, Kathryn Saynor
Publikováno v:
Journal of Organometallic Chemistry. 565:141-151
The μ3-benzyne complex [Ru3(CO)7(μ-PPh2)2(μ3-C6H4)] (1a) reacts at room temperature (r.t.) with carbon monoxide (1 atm), trimethylphosphite, or t-butylisocyanide to give complexes [Ru3(CO)6L2(μ-PPh2)2(μ3-C6H4CO)] (2a, L=CO; 2b, L=P(OMe)3; 2c, L=
Autor:
Josep M. Viñas, Jonathan P. H. Charmant, Selby A. R. Knox, Nigel J. Grist, Jerome B. Keister, A. Guy Orpen, David A. V. Morton, Helen A. A. Dickson
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1393-1395
Carbonylation (1 atm, 25 °C) of [Ru3(CO)7(µ-PPh2)2(µ3-C6H4)] gives [Ru3(CO)8(µ-PPh2)2(µ3-C6H4CO)], arising from linking of µ3-benzyne with one molecule of CO, while [Ru4(CO)11(µ4-PPh)(µ4-C6H4)] and [Ru5(CO)13(µ4-PPh)(µ5-C6H4)] react with CO