Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Heike Haller"'
Publikováno v:
European Journal of Inorganic Chemistry. 2018:3330-3337
Publikováno v:
Angewandte Chemie International Edition. 54:15579-15583
In a eutectic mixture of two ionic liquids, we have synthesized and crystallized the new polychloride compound [Et4 N]2 [(Cl3 )2 ⋅Cl2 ] that exhibits a periodic 2D polychloride network acting as an anionic layer. Based on its low melting point and
Publikováno v:
Angewandte Chemie. 127:15800-15804
Aus einem Eutektikum zweier ionischer Flussigkeiten wurde das neuartige Polychlorid [Et4N]2[(Cl3)2⋅Cl2] kristallisiert, welches eine anionische Schichtstruktur aus einem 2D-Polychloridnetzwerk besitzt. Aufgrund ihres niedrigen Schmelzpunkts und Dam
Autor:
Sebastian Riedel, Heike Haller
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 640:1281-1291
In this review we discuss the recent discoveries in polyhalide anion chemistry with the main focus on polybromide, -chloride, and -fluoride anions. Based on novel synthetic strategies either in ionic liquids or in neat halogens several new polyhalide
Publikováno v:
Synthesis. 46:740-747
Tetrapropylammonium nonabromide (Pr4NBr9) is introduced as a room-temperature solid reagent for rapid bromination reactions of various substrates. The reagent exhibits reactivity similar to that of elemental bromine, but shows higher selectivity and
Autor:
Harald Scherer, Franziska Scholz, Ingo Krossing, Heike Haller, Sebastian Riedel, Michael Stephan Hog
Publikováno v:
Zeitschrift für Naturforschung B. 68:1103-1107
[HMIM][Br9] ([HMIM]=1-hexyl-3-methylimidazolium) has been investigated by Raman spectroscopy, single-crystal X-ray diffraction and NMR spectroscopy. Conductivity measurements show a high electrical conductivity like other polybromides.
Publikováno v:
Angewandte Chemie. 125:5037-5040
Publikováno v:
Chemistry - A European Journal. 18:5741-5747
Polychloride monoanions stabilized by quaternary ammonium salts are investigated using Raman spectroscopy and state-of-the-art quantum-chemical calculations. A regular V-shaped pentachloride is characterized for the [N(Me)(4)][Cl(5)] salt, whereas a
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 638:553-558
Polybromide monoanions of the series [NAlk4][Br9] (Alk = methyl, ethyl, propyl, butyl) have been investigated. The corresponding salts were characterized by Raman spectroscopy, single-crystal X-ray diffraction and state-of-the-art quantum-chemical ca
Publikováno v:
Angewandte Chemie. 123:11732-11736