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Autor:
Julie L. Brown, Kristen J. Babinski, Patricia O'Brien, Michelle R. Durwin, Ted R. Foss, Rachel E. Campbell, Michael C. Bouteneff, Martha S. Reynolds, Mary A. Cowan, Heather R. Penn
Publikováno v:
Inorganica Chimica Acta. 263:225-230
The kinetics of bromide oxidation by several peroxo complexes of molybdenum(VI) and tungsten(VI) wre studied. All system obey the rate law d[Br + ]/d t = k [etal complex][Br − ]. At pH 1.0, we quantify the initial rate of bromine production by the