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Publikováno v:
Polymer Chemistry. 12:5048-5058
Poly(δ-pinene), PδP, is a promising new material derived from naturally abundant α-pinene. One of the persistent by-products in the synthesis of δ-pinene is α-pinene which required intensive and non-sustainable isocyanate chemistry to fully remo
Publikováno v:
ACS macro letters. 10(6)
Well-controlled ring-opening metathesis polymerization (ROMP) of δ-pinene is reported. The monomer is produced through a facile, metal-free, three-step synthesis from highly abundant and sustainable α-pinene. Using Grubbs third-generation catalyst,