Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Hassan Osseili"'
Autor:
Hassan Osseili, Daniel F. Sauer, Klaus Beckerle, Marcus Arlt, Tomoki Himiyama, Tino Polen, Akira Onoda, Ulrich Schwaneberg, Takashi Hayashi, Jun Okuda
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 12, Iss 1, Pp 1314-1321 (2016)
Copper(I) and copper(II) complexes were covalently linked to an engineered variant of the transmembrane protein Ferric hydroxamate uptake protein component A (FhuA ΔCVFtev). Copper(I) was incorporated using an N-heterocyclic carbene (NHC) ligand equ
Externí odkaz:
https://doaj.org/article/0df5477da41e4c308da3090edc92919d
Publikováno v:
Angewandte Chemie. 131:1847-1851
Publikováno v:
Angewandte Chemie International Edition. 58:1833-1837
Facile α-H elimination from tetrakis(trimethylsilylmethyl)titanium precursors to give adducts of (alkylidene)bis(alkyl)titanium complexes is induced by light alkali metal amides of the NNNN-type macrocyclic anionic ligand Me3 TACD [(Me3 TACD)H=1,4,7
Autor:
Khai-Nghi Truong, Thomas P. Spaniol, Jun Okuda, Hassan Osseili, Debabrata Mukherjee, Ulli Englert
Publikováno v:
Chemistry - A European Journal. 23:17213-17216
A series of light alkali metal organoperoxides [MOOR] (M = Li, Na, K; R = tBu, CMe2Ph) were isolated in mononuclear form, aided by the tetradentate and neutral NNNN-type macrocycle Me4TACD (L; Me4[12]aneN4 = 1,4,7,10-tetramethyl-1,4,7,10-tetraazacycl
Publikováno v:
Chemistry - A European Journal. 23:14292-14298
Alkali metal hydridotriphenylborates [(L1 )M][HBPh3 ] (L1 =Me6 TREN; M=Li, Na, K) chemoselectively catalyze the hydroboration of carbonyls and CO2 , with lithium being the most active system. A new series of complexes [(L2 )M][HBPh3 ] [M=Li (1), Na (
Publikováno v:
Organometallics. 36:3029-3034
Triphenylborane (BPh3) abstracted the β-SiH in [(L)M{N(SiHMe2)2}] (L = Me6TREN; M = Li, Na, K) in THF to give the hydridotriphenylborates [(L)M][HBPh3]. Reactions in benzene favored silazide instead of hydride abstraction to give [(L)M][Ph3B–N(SiH
Publikováno v:
Dalton Transactions. 46:8017-8021
The macrocyclic polyamine 1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane [LH = (Me3TACD)H] formed adducts with tetramethyl-silazides [M{N(SiHMe2)2}] (M = Li, Na, K) of light alkali metals. Upon heating, intramolecular dehydrocoupling occurred to give
Publikováno v:
Chemical Communications. 53:3493-3496
Molecular aluminum hydride [(L)AlH2] (L = Me3TACD) reacted with 2 equiv. of BPh3 in THF or THP to give the cationic alkoxides [(L)Al(OR)][HBPh3] (R = nBu, nPent) by facile ring-opening of the cyclic ethers. The Cα–O bond cleavage which involves th
Publikováno v:
Journal of the American Chemical Society. 138:10790-10793
Light alkali metal hydridotriphenylborates M[HBPh3] (M = Li, Na, K), characterized as tris{2-(dimethylamino)ethyl}amine (L) complexes [(L)M][HBPh3], act as efficient catalysts for the chemoselective hydroboration of a wide range of aldehydes and keto
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 23(57)
Alkali metal hydridotriphenylborates [(L