Zobrazeno 1 - 10
of 42
pro vyhledávání: '"Hartmut Schönberg"'
Autor:
Hansjörg Grützmacher, Peter Murer, Jean-Pierre Wolf, Souad Boulmaaz, Reinhard H. Sommerlade, Hartmut Schönberg, Timo Ott, Daniel Stein, Jens Geier, Thomas Ulrich
Publikováno v:
CHIMIA, Vol 62, Iss 1-2 (2008)
A straightforward high-yield synthesis for the photoinitiator bis(2,4,6-trimethylbenzoyl)phenylphosphane oxide (16, IRGACURE 819) involves: i) the reaction of phenyldichlorophosphane, PhPCl2, with sodium to give [Na2(P2Ph2)(tmeda)]6 (5); ii) protona
Externí odkaz:
https://doaj.org/article/38970b9dfc56408a8517742cbec73049
Publikováno v:
CHIMIA, Vol 59, Iss 3 (2005)
The reaction of phenyldichlorophosphane, PhPCl2, a commercially important precursor for organophosphorus compounds, with lithium and sodium as reducing metals was re-investigated with the aim to well-characterize the resulting oligophosphandiides, [M
Externí odkaz:
https://doaj.org/article/b4245ab01568482fb2981e0d77232f91
Autor:
Carsten Böhler, Christoph Widauer, Markus Scherer, Hartmut Schönberg, Nicola Pè, Pascal Maire, Sandra Loss, Florian Läng, Cécile Laporte, Jens Geier, Gilles Frison, Gionata Frasca, Stephan Deblon, Torsten Büttner, Hansjörg Grützmacher
Publikováno v:
CHIMIA, Vol 55, Iss 10 (2001)
The dibenzo[a,d]cycloheptatrienyl residue is introduced as platform for the high-yield synthesis of new rigid phosphanes (tropp ligand system) and phosphiranes (BABAR-phos); strained three-membered heterocycles. With tropp as ligands, transition meta
Externí odkaz:
https://doaj.org/article/eaa3af3c9b32401d9ca5f255775136ba
Autor:
Anna Widera, Debora Thöny, Marcel Aebli, Julius Jacob Oppenheim, Justin L.Andrews, Frederik Eiler, Michael Wörle, Hartmut Schönberg, Norbert Weferling, Mircea Dincǎ, Hansjörg Grützmacher
Publikováno v:
Angewandte Chemie. 135
Autor:
Anna Widera, Debora Thöny, Marcel Aebli, Julius Jacob Oppenheim, Justin L. Andrews, Frederik Eiler, Michael Wörle, Hartmut Schönberg, Norbert Weferling, Mircea Dincǎ, Hansjörg Grützmacher
Publikováno v:
Angewandte Chemie. International Edition, 62 (13)
Phosphane, PH3—a highly pyrophoric and toxic gas—is frequently contaminated with H2 and P2H4, which makes its handling even more dangerous. The inexpensive metal–organic framework (MOF) magnesium formate, α-[Mg(O2CH)2], can adsorb up to 10 wt
Autor:
Hansjörg Grützmacher, Vijay Kumar Rana, Frank Krumeich, Bodo Hattendorf, Hartmut Schönberg, Debora Käser, Amos J. Rosenthal, Zoltán Benkő, Zhongshu Li, Georgina Müller, Andreas Beil
Publikováno v:
Angewandte Chemie. 130:7823-7828
Bismesitoylphosphinic acid, (HO)PO(COMes)2 (BAPO-OH), is an efficient photoinitiator for free-radical polymerizations of olefins in aqueous phase. Described here are the structures of various copper(II) and copper(I) complexes with BAPO-OH as the lig
Autor:
A. Huber, Hansjörg Grützmacher, Hartmut Schönberg, Joëlle Levalois-Grützmacher, Frank Krumeich, Daniel Stein, Andreas Kuschel, Timo Ott, Gustavo Santiso-Quinones, Reinhard Kissner, Judith Bräuer
Publikováno v:
Angew. Chem. Int. Ed
Keywords: phosphorus; photoinitiators; polymers; radical polymerization; surface modification Thumbnail image of graphical abstract Got a light? An efficient method for the synthesis of phosphorus functionalized bis(acyl)phosphaneoxides (BAPOs) was d
Autor:
Hartmut Schönberg, Daniel Stein, Jeffrey Harmer, Martin Königsmann, Nicola Donati, Anandaram Sreekanth, Hansjörg Grützmacher
Publikováno v:
Angewandte Chemie. 119:3637-3640
Autor:
Frank Breher, Daniel Stein, Markus Scherer, Jens Geier, Hartmut Schönberg, Hansjörg Grützmacher
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 631:2770-2774
Pentaphenylcyclopentaphosphane, c-(P5Ph5) is conviently prepared from PhPCl2 and thermally activated zinc powder in thf. Hydrolysis of c-(P5Ph5) in the presence of ZnCl2 gives to an equimolar distribution of PhPH2, PhP(=O)H2, and PhP(=O)(OH)H. Reacti
Publikováno v:
Organometallics. 24:3207-3218
The chiral tetrachelating amino−olefins (R,R)-N,N‘-bis(5H-dibenzo[a,d]cyclohepten-5-yl)-1,2-diaminocyclohexane ((R,R)-trop2dach) and (S,S)-N,N‘-bis(5H-dibenzo[a,d]cyclohepten-5-yl)-1,2-diphenyl-1,2-ethylenediamine ((S,S)-trop2dpen) were prepare