Zobrazeno 1 - 10
of 155
pro vyhledávání: '"Hartmut B. Stegmann"'
Autor:
Hartmut B. Stegmann, Vitaly A. Roginsky, Gabriele Seitz, Dietrich Niethammer, Zyrafete Kuçi, Gernot Bruchelt, Hartwig Wolburg
Publikováno v:
Medical and Pediatric Oncology. 35:612-615
BACKGROUND 6-Hydroxydopamine (6-OHDA) was used for ex vivo purging of bone marrow from neuroblastoma cells before autologous transplantation. However, this concept failed because of the rapid autoxidation of 6-OHDA, which leads to the generation of c
Publikováno v:
Magnetic Resonance in Chemistry. 37:805-813
The question regarding chirality in nitroxides was rigorously investigated, namely, (a) are multiple EPR and ENDOR spectra expected from nitroxides with chiral centers, (b) which structures provide multiple structures and (c) under what conditions (t
Publikováno v:
Monatshefte für Chemie / Chemical Monthly. 130:451-470
The synthesis of enantiomerically pure 5- and 6-chloroepinephrine hydrochloride, resp., as well as 6-chloronorepinephrine hydrochloride is described starting from ring chlorinated O-benzylated dihydroxybenzaldehyde cyanohydrins, which are O-protected
Publikováno v:
Zeitschrift für Naturforschung B. 53:1511-1519
Molecular recognition between Rebek’s cleft R and 4-(2-benzimidazolyl)-aminomethyl-2,6-di-rm-butyl-phenol (Bi) is investigated by means of EPR spectroscopy. Their specific inter-molecular interactions are distinguished from non-specific interaction
Publikováno v:
Magnetic Resonance in Chemistry. 36:422-428
The synthesized spin trap 3,5-diphenyl-5-methylpyrroline-1-oxide (3), its derivatives and spin adducts were studied using NMR, ESR and ENDOR spectroscopic methods. The structure of 3 was determined using x-ray analysis. The nitrone 3 was found to hav
Publikováno v:
Magnetic Resonance in Chemistry. 36:205-210
Autor:
Hartmut B. Stegmann, Martin Jäger
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :697-700
A variety of 2,6-di-tert-butyl-4-(N,N-disubstituted aminomethyl)phenoxyl radicals have been studied with respect to the para substituents’ and meta protons’ coupling constants observed in EPR and ENDOR experiments. For all molecules considered, r
Publikováno v:
Zeitschrift für Naturforschung C. 52:380-390
Comparative kinetic studies on the oxidation of catecholamines (CA) (dopamine (DA), epinephrine (EP). norepinephrine (NEP)) serving as a neuromediator in the sympathetic nervous system, 3,4-dihydroxyphenylalanine (DOPA) and 6-hydroxydopamine (6-OHDA)
Publikováno v:
Biochimica et Biophysica Acta (BBA) - General Subjects. 1335:33-39
Ferritin is the main intracellular iron storage protein. Ferritin iron may be released by many reducing agents including ascorbate. In this work we report ferritin to catalyze the oxidation of ascorbate. The kinetics of this process were studied in d
Autor:
Gerhard Raabe, J. Henrique Teles, Ahmed Ghanimi, Dieter Enders, Hartmut B. Stegmann, Klaus Breuer, Jacques Simonet
Publikováno v:
Tetrahedron Letters. 38:2833-2836
The electrochemical reduction of the carbene 1 reversibly yielded the corresponding radical anion 2 , which was characterized by ESR measurements. Ab initio calculations provided a better understanding of its structure and stability.