Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Harold Gershinowitz"'
Publikováno v:
The Journal of Chemical Physics. 3:479-489
In this paper the considerations of the previous paper have been developed further and compared with the theory of reaction rates as formulated in terms of a specifically defined activated complex by Eyring. The theory has been applied to a discussio
Autor:
Harold Gershinowitz, E. Bright Wilson
Publikováno v:
The Journal of Chemical Physics. 6:247-251
The infra‐red absorption spectra of gaseous cis‐ and transbutene‐2 have been measured with a prism spectrometer from 435 to 4000 cm—1. The Raman spectra of these compounds as liquids have also been obtained. The accepted identification of the
Publikováno v:
Industrial & Engineering Chemistry. 54:23-32
Autor:
E. Bright Wilson, Harold Gershinowitz
Publikováno v:
The Journal of Chemical Physics. 6:197-200
A spectrometer has been constructed which contains two prisms, one of NaCl, the other of KBr, each in a Wadsworth‐Littrow mounting. The prisms may be interchanged in the optical train without opening the spectrometer housing or disturbing the calib
Autor:
Harold Gershinowitz
Publikováno v:
Research Management. 12:205-218
Autor:
Harold Gershinowitz, Henry Eyring
Publikováno v:
Journal of the American Chemical Society. 57:985-991
Entropy and the Absolute Rate of Chemical Reactions I. The Steric Factor of Bimolecular Associations
Publikováno v:
The Journal of Chemical Physics. 2:853-861
The equilibrium constant for a bimolecular association may be expressed in terms of the energy change, ΔE, and standard entropy change, ΔS°, on association. On account of the well‐known relation between the equilibrium constant, and the rate con
Autor:
Harold Gershinowitz
Publikováno v:
The Journal of Chemical Physics. 4:363-366
The theories of the rates of chemical reactions previously developed by Eyring, Rice and the author give a relationship between the rate of reaction and the free energy of formation of the activated state. With the aid of this relation it is possible
Publikováno v:
The Journal of Chemical Physics. 2:273-282
By using the principle of microscopic reversibility, unimolecular decompositions are considered from the point of view of the reverse reaction, which is a bimolecular association. In cases where the immediate product of the decomposition is a pair of
Autor:
Henry Eyring, Harold Gershinowitz
Publikováno v:
The Journal of Chemical Physics. 3:224-229
By means of simple operators derived from the antisymmetrical configuration eigenfunctions a method is devised for obtaining the coefficients in the expansion of a bond eigenfunction in terms of a linearly independent set. This method eliminates any