Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Harini Kilambi"'
Autor:
Sirish K. Reddy, Harini Kilambi, Jeffrey W. Stansbury, Lauren Schneidewind, Christopher N. Bowman
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 47:4859-4870
The impact of secondary functionalities on the radical-vinyl chemistry of monoacrylates characterized by secondary functionalities that dramatically enhance their polymerization rate was elucidated utilizing experimental and computational techniques.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7e13d8d7c9410aefa498fb21e860e066
https://doi.org/10.1002/pola.23503
https://doi.org/10.1002/pola.23503
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 46:3452-3458
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::21b6a09cc05818f68d4b6b9d4c340b2a
https://doi.org/10.1002/pola.22660
https://doi.org/10.1002/pola.22660
Publikováno v:
Macromolecules. 40:6131-6135
In this particular study, the reaction mechanisms of bulk polymerization of acrylates in the presence of tetraethylthiuram disulfide (TED) are investigated using hexyl acrylate as a model acrylate. TED's presence impacts the termination mechanisms of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a11f315e8cf9c9109950e80295a99557
https://doi.org/10.1021/ma070187f
https://doi.org/10.1021/ma070187f
Autor:
Tai Yeon Lee, Sirish K. Reddy, Christopher N. Bowman, Harini Kilambi, Jeffrey W. Stansbury, Lauren Schneidewind
Publikováno v:
Macromolecules. 40:6112-6118
This study focuses on the design and development of novel monovinylic (meth)acrylate monomers with enhanced polymerization kinetics and the evaluation of their performance as reactive diluents in diacrylate systems. Novel (meth)acrylic monomers chara
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::072d7db64bec9613811a9e6817c6b743
https://doi.org/10.1021/ma062708p
https://doi.org/10.1021/ma062708p
Autor:
Jeffrey W. Stansbury, Sirish K. Reddy, Christopher N. Bowman, Harini Kilambi, Lauren Schneidewind
Publikováno v:
Polymer. 48:2014-2021
The copolymerization behavior and the dark polymerization kinetics of highly reactive novel acrylic monomers were compared to traditional acrylate monomers. Copolymerization of thiol functionalities with novel acrylic monomers was characterized, and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f2f242bb068de3ceed52b17d921ba06
https://doi.org/10.1016/j.polymer.2007.02.006
https://doi.org/10.1016/j.polymer.2007.02.006
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 45:1287-1295
Here we demonstrate that acrylates exhibit significant rate reductions in the presence of small concentrations of protic acids (0.1–0.5 wt %) compared with the bulk monomer concentration. Dramatically different sensitivities to acid inhibition, dif
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7bd31ee9785f3bd46636a892888fce5c
https://doi.org/10.1002/pola.21897
https://doi.org/10.1002/pola.21897
Publikováno v:
Macromolecules. 40:47-54
Polymerization studies in the presence of extensive amounts of solvent are used here to deconvolute the effects of intermolecular interactions such as bulk medium polarity, π−π stacking, and hydrogen bonding and characterize the contribution of i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1832d0ebfca22dd00e2dc82c54f9d8a9
https://doi.org/10.1021/ma0619839
https://doi.org/10.1021/ma0619839
Autor:
Kathryn A. Berchtold, Eric R. Beckel, Harini Kilambi, Jeffrey W. Stansbury, Christopher N. Bowman
Publikováno v:
Polymer. 46:4735-4742
Numerous acrylate monomers have been synthesized and evaluated extensively as a means to explore the relationship between molecular polarity and monomer reactivity. Various monomers, characterized by high values of dipole moment, were polymerized in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e91e569de01a3d24cc2854837f0a92e2
https://doi.org/10.1016/j.polymer.2005.04.006
https://doi.org/10.1016/j.polymer.2005.04.006
Autor:
Eric R. Beckel, and Jeffrey W. Stansbury, Sirish K. Reddy, Harini Kilambi, Christopher N. Bowman
Publikováno v:
Chemistry of Materials. 19:641-643
It was observed that the incorporation of secondary functionalities in a (meth)acrylic monomer causes up to 3 orders of magnitude enhancement in the Michael addition reaction rates for amine-catalyzed Michael addition with thiols. Further, a distinct
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0babf931df3b4ef2debb6955fd18bf0c
https://doi.org/10.1021/cm070077n
https://doi.org/10.1021/cm070077n
Autor:
Harini Kilambi, Jeffrey W. Stansbury, Christopher N. Bowman, Parag K. Shah, Neil B. Cramer, Lauren Schneidewind
Publikováno v:
Dental materials : official publication of the Academy of Dental Materials. 25(1)
Objectives This study evaluates the performance of highly reactive novel monomethacrylates characterized by various secondary moieties as reactive diluent alternatives to TEGDMA in BisGMA filled dental resins. We hypothesize that these monomers impro
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b6eb912f2f90e515ed039e0fd54fd165
https://pubmed.ncbi.nlm.nih.gov/18584862
https://pubmed.ncbi.nlm.nih.gov/18584862