Zobrazeno 1 - 10
of 112
pro vyhledávání: '"Harald Scherer"'
Autor:
Andreas Billion, Marcel Schorpp, Rebecca Feser, Manuel Schmitt, Lea Eisele, Harald Scherer, Takaaki Sonoda, Hajimu Kawa, Burkhard Butschke, Ingo Krossing
Publikováno v:
Dalton Transactions. 52:4355-4370
Dream WCA…? The very high fluoride ion affinity of the Lewis acid underlying the novel WCA [Al(OC10F15)4]− ([pfAd]−) nurtures the hope for having found a new “dream WCA”. Yet, the paths towards this WCA held some obstacles at hand...!
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8e3e158f46ed4a8090085909775c85f6
https://doi.org/10.1039/d3dt00199g
https://doi.org/10.1039/d3dt00199g
Publikováno v:
Chemical Communications. 59:1353-1356
We herein present the structures of two novel dicationic gallium dimers, a digallane and a digallene, as well as a detailed bonding analysis of the highly unusual bonding situations.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ec72da1eceed5b78513322cf57bd4cfe
https://doi.org/10.1039/d2cc06377h
https://doi.org/10.1039/d2cc06377h
Publikováno v:
Chemical Science. 13:439-453
Already 1 mol-% of subvalent [Ga(PhF)2]+[pf]– ([pf]– = [Al(ORF)4]– , RF = C(CF3)3) initiates the hydrosilylation of olefinic double bonds under mild conditions. Reactions with HSiMe3 and HSiEt3 as substrates efficiently yield anti-Markovnikov a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2bc44aea24587c154c4e5f60fd14e955
https://doi.org/10.1039/d1sc05331k
https://doi.org/10.1039/d1sc05331k
Publikováno v:
Chemistry – A European Journal. 28
The tetracationic, univalent cluster compounds [{M(dmpe)}
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a2eff912fc284fea866c4fe5f661e264
https://doi.org/10.1002/chem.202201369
https://doi.org/10.1002/chem.202201369
Publikováno v:
Journal of Magnetic Resonance. :107476
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7968c81c3ae38f30585d13dddc666fb0
https://doi.org/10.1016/j.jmr.2023.107476
https://doi.org/10.1016/j.jmr.2023.107476
Publikováno v:
Angewandte Chemie (International Ed. in English)
The potential of a dicationic strontium ansa‐arene complex for Lewis acid catalysis has been explored. The key to its synthesis was a simple salt metathesis from SrI2 and 2 Ag[Al(ORF)4], giving the base‐free strontium‐perfluoroalkoxyaluminate S
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c7948db03e07e94ac2c0ac4d20db43c
https://doi.org/10.1002/anie.202010019
https://doi.org/10.1002/anie.202010019
Publikováno v:
Inorganic Chemistry. 59:9496-9510
The PPh3 ligands in the heterodinuclear AuPt complex [(Ph3P)AuPt(PPh3)3][BAr4F] (BAr4F = tetrakis[3,5-bis(trifluoromethyl)phenyl]borate) exhibit a high fluxionality on the AuPt core. Fast intramole...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9277fffa6b4f95266f1e1abeb94a9b27
https://doi.org/10.1021/acs.inorgchem.9b03622
https://doi.org/10.1021/acs.inorgchem.9b03622
Autor:
Konstantin Koessler, Harald Scherer, Burkhard Butschke, Lukas D. Ernst, Daniel Kratzert, Andreas Peter
Publikováno v:
Chemical Communications. 56:5350-5353
[(Ph3P)AuPt(nbe)3][BAr4F] (nbe = norbornene) constitutes the first olefin-containing, formal Au+IPt0 complex. The unusual coordination mode and the electronic properties have been analyzed spectroscopically and by calculations. The low binding energy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5e74e7535e697a3a4ee01af9518abbb1
https://doi.org/10.1039/d0cc01719a
https://doi.org/10.1039/d0cc01719a
Publikováno v:
Angewandte Chemie (International Ed. in English)
The reaction of the Ga+ source [Ga(PhF)2]+[Al(ORF)4]− with the neutral σ‐donor ligand dmap (4‐Me2N‐C6H4N) produces the unexpectedly large and fivefold positively charged cluster cation salt [Ga5(dmap)10]5+([Al(ORF)4]−)5. It includes a regu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b55678356ab45834a94c5547512ea10a
https://doi.org/10.1002/ange.201907974
https://doi.org/10.1002/ange.201907974
Publikováno v:
Chemistry – A European Journal. 25:12159-12168
The complexes Ag(L)n [WCA] (L=P4 S3 , P4 Se3 , As4 S3 , and As4 S4 ; [WCA]=[Al(ORF )4 ]- and [F{Al(ORF )3 }2 ]- ; RF =C(CF3 )3 ; WCA=weakly coordinating anion) were tested for their performance as ligand-transfer reagents to transfer the poorly solub
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7cf984088b2d8c5dafc87970fe7022ef
https://doi.org/10.1002/chem.201902339
https://doi.org/10.1002/chem.201902339