Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Harald Neubacher"'
Publikováno v:
Zeitschrift für Naturforschung C. 37:553-557
ESR spectra of platinum uracil “blue” are discussed. Two main types o f paramagnetic species have been found, one of which can be explained by assuming an unpaired electron spin delocalized over dz²-orbitals of two equivalent Pt centers, the oth
Publikováno v:
Radiation and Environmental Biophysics. 13:305-313
Electron spin resonance and optical absorption studies have been done in order to investigate the interaction between Cu2+ and aromatic amino acids in aqueous solution at 77 K and at room temperature as well. Depending on the concentration each aroma
Publikováno v:
Zeitschrift für Naturforschung B. 34:1015-1018
cts-Dichlorodiammine platinum(II), which is known to be an active anticancer compound, and tryptophan form paramagnetic complexes in aqueous solution. These can be detected by means of electron spin resonance spectroscopy (ESR) after a reaction time
Publikováno v:
Zeitschrift für Naturforschung C. 33:321-325
The interaction of Cu (II) with the protein pepsin has been investigated by means of electron spin resonance (ESR) and optical spectroscopy. Depending on the molar ratio of Cu(II) and pepsin in aqueous solution two different complexes are formed. A t
Publikováno v:
Radiation and Environmental Biophysics. 13:49-56
Experiments on the production of free radicals in aqueous solutions of N-methyl and N-acetyl substituted amino acids by UV light are reported. The ESR spectra observed at 77 K show that the bond of the CH3- group of these substances is ruptured to a
Autor:
Harald Neubacher
Publikováno v:
Biophysik. 7:47-54
Es werden Sattigungsmessungen der Elektronenspinresonanzspektren strahleninduzierter Radikale mehrerer Kohlenhydrate beschrieben. Dazu wird einSattigungs-parameter definiert, der bei homogener und inhomogener Linienverbreiterung anzuwenden ist und mi
Publikováno v:
Zeitschrift für Naturforschung B. 36:651-653
Frozen samples of aqueous solutions of oxidized Pt 6-methyl-uracil “blue” were studied by ESR spectroscopy at temperatures T ranging between - 196 °C and - 10 °C. When T was raised a distinct change in the line pattern was observed at about -35
Publikováno v:
Zeitschrift für Naturforschung B. 37:790-792
The ESR spectra of novel paramagnetic comple-xes between cis-dichlorodiammineplatinum(II) and cytosine or cytidine in aqueous solution are presented and discussed. The results imply a complex containing a binuclear metal-metal bonded platinum moiety
Publikováno v:
Zeitschrift für Naturforschung B. 36:272-274
The observation of a new type of ESR spectrum in the course of redox experiments on a platinum uracil "blue" compound is reported. Some characteristic features of the ESR and optical absorption spectra are described. A tentative analysis of the ESR s
Autor:
Harald Neubacher
Publikováno v:
Zeitschrift für Naturforschung C. 39:174-176
The main contribution to ESR spectra of lyophilized tissues of plant or animal origin usually is given by an anisotropic singlet, which is known to be caused at least in the majority of cases by the adsorption of an ascorbyl radical. Model systems ha