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Publikováno v:
Tetrahedron Letters, 40, 4255-4258. Elsevier
Various isoquinolines and pyridines were prepared from aryl- and vinyl halides by a method which involves insertion of an allene into the PdC bond and intramolecular nucleophilic attack of the imine.
Publikováno v:
Tetrahedron Letters. 39:4111-4114
1,1-Dimethylallene inserts into the σ PdC bond of cyclopalladated α-tetralone ketimines leading to stable new heterocycles after depalladation. Intramolecular attack of an imine on a Pd-allyl complex leads to the formation of iminium salts which