Výsledky vyhledávání - "Hans-Gert Korth"

Comment on 'Persistent Room‐Temperature Radicals from Anionic Naphthalimides: Spin Pairing and Supramolecular Chemistry' and on 'Persistent Radical Pairs between N‐Substituted Naphthalimide and Carbanion Exhibit p K a‐Dependent UV/Vis Absorption'

Autor: Hans-Gert Korth

Publikováno v: Chemistry – A European Journal. 26:12747-12750

EPR spectroscopic evidence for intramolecular electron transfer in anionic N-substituted naphthalimides to yield persistent diradical anions and intermolecular electron transfer from a variety of carbanions to 6-bromo-N-phenyl-naphthalimide to yield

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b09a8c352361b74362c98bab0ae04608
https://doi.org/10.1002/chem.202003437

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Comment on 'Photochemical Activities of N ‐Nitroso Carboxamides and Sulfoximides and Their Application to DNA Cleavage'

Autor: Hans-Gert Korth

Publikováno v: Chemistry – A European Journal. 27:1473-1475

This Correspondence reports on a structural and mechanistic misinterpretation of an observed EPR spectrum, a misleading presentation of DNA cleavage data, and the physicochemically unsupported assignment of nitric oxide as a major DNA cleaving agent

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b413da4b9a9095d2f42972898e16c524
https://doi.org/10.1002/chem.201500428

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Phenolic Hydrogen Transfer by Molecular Oxygen and Hydroperoxyl Radicals : Insights into the Mechanism of the Anthraquinone Process

Autor: Hans-Gert Korth, Peter Mulder

Publikováno v: The Journal of Organic Chemistry

Hydrogen atom transfer (HAT) by 3O2 and HO2• from arenols (ArOH), aryloxyls (ArO•), their tautomers (ArH), and auxiliary compounds has been investigated by means of CBS-QB3 computations. With 3O2, excellent linear correlations have been found bet

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::58fdc371a5f467e8371db79fd3c589ed
https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&origin=inward&scp=85080848167

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Comment on 'trans-1,2-Disiloxybenzocyclobutene, an adequate partner for the auto-oxidation: EPR/spin trapping and theoretical studies' by J. Drujon et al., Phys. Chem. Chem. Phys., 2014, 16, 7513

Autor: Peter Mulder, Hans-Gert Korth, Thomas Paul

Publikováno v: Physical Chemistry Chemical Physics. 19:3405-3408

Despite the claim of the contrary, (i) the facile formation of a ring-opened cyclic peroxide from reaction of a 1,2-disubstituted benzocyclobutene with molecular oxygen has been reported before, and (ii) the analysis of the mechanistic steps of this

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dc10ca7c6ac6f99ccf05a8f4266700b3
https://doi.org/10.1039/c6cp04187f

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