Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Hans Vansweevelt"'
Publikováno v:
The Journal of Organic Chemistry. 59:8015-8022
Publikováno v:
Chemische Berichte. 125:923-927
Ab initio MO calculations at the MP4/6–31G** level show that both fluorine and chlorine atoms exert a strong stabilizing effect on the three-membered ring 1H-phosphirene relative to its isomers. While unsubstituted 1H-phosphirene (12H) is the least
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1425-1427
Ab initio MO calculations show that F2PN is remarkably stable, lying about 70 kJ mol–1 lower in energy than its conventional valence isomer difluoro-iminophosphane (FPNF) and could thus be a candidate for an actual synthesis in the laboratory.
Publikováno v:
Vaccines; Jun2023, Vol. 11 Issue 6, p1116, 24p