Zobrazeno 1 - 10
of 239
pro vyhledávání: '"Hans Suschitzky"'
Publikováno v:
Journal of Heterocyclic Chemistry. 36:1001-1012
Nucleophilic reactions of two 2,2′-bisbenzimidazole systems, namely the bis(2H-benzimidazole-2-ylidene) 2 and the dispiro[2H-benzimidazole-2,1′-cyclohexane-4′,2″-2″H-benzimidazole] 3, as well as the syntheses of new 2,2′-bisbenzimidazoles
Publikováno v:
Journal of Heterocyclic Chemistry. 36:117-128
The readily available title compounds 2, 16 and 27 react with pseudohalogenes (cyanide, azide), carbon and heterocyclic N-nucleophiles in the presence of manganese dioxide to give the corresponding substituted azaisobenzimidazoles (= 2H-azabenzimidaz
Publikováno v:
Tetrahedron. 51:10771-10794
Polysubstiluted o -phenylenediamines were syathesised in moderate to high yield by reductive cleavage of the corresponding 2 H -benzimidazole-2-spirocyclohexane with sodium dithionite in aqueous ethanol and converted into methyl benzimidazole-2-carba
Publikováno v:
Tetrahedron. 51:5597-5608
The title compound 1 was prepared by condensation of 3,5-dibromo- o -phenylenediamine 10 with cyclohexanone and oxidation of the resulting 4,6-dibromo-1,3-dihydro-2 H -benzimidazole-2-spirocyclohexane 5 with manganese dioxide. With sodium 2,3-dichlor
Publikováno v:
Helvetica Chimica Acta. 77:2175-2190
The readily available title compounds 4a and 24 react with N-, O-, S-, and C-nucleophiles in presence of MnO2 to give the corresponding mono- or disubstituted 2H-azabenzimidazoles ( = azaisobenzimidazoles), e.g., 11–18 and 26a–h, respectively, or
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
The reverse addition of 2-lithio-1,6-methanol[10]annulene (2-lithio-1,6-methanocyclodecapentaene) to some group VI metal crabony compounds followed by alkylation with meerwein salts gave the E. O. Fischer transition metal complexes in good to excelle
Publikováno v:
ChemInform. 23
The products obtained by treating 2H-benzimidazole-2-spirocyclohexane 1 or its 5-chloro derivative 9 with various thiols (PrSNa, ButSNa, PhSNa, pyridine-2-thiol, or pyrimidine-2-thiol) depend on the reaction conditions. Monosubstitution is possible a
Autor:
Peter Kutschy, Andrew G. Robinson, Franz A. Neugebauer, Hans Suschitzky, Walter Kramer, Brian Iddon
Publikováno v:
ChemInform. 24
A new synthesis of the selective anthelmintic agent triclabendazole 7 from the readily available 5,6-dichloro-2H-benzimidazole-2-spirocyclohexane 2 by simple steps is described. Analogous benzi-midazoles difficult to prepare by conventional methods a
Publikováno v:
ChemInform. 25