Zobrazeno 1 - 10
of 860
pro vyhledávání: '"Hans R. Kricheldorf"'
Publikováno v:
Journal of Polymer Science. 60:3222-3231
Publikováno v:
Macromolecular Chemistry and Physics.
Publikováno v:
Materials Advances. 3:1007-1016
Experiments are performed to obtain the highest Tm and ΔHm values for poly(l-lactide)s. They also include comparison with literature data and of cyclic and linear species.
Publikováno v:
Polymer Chemistry. 13:1177-1185
Strong protic acids catalyze intermolecular transesterification in reversible polyester syntheses even at low temperatures (109 °C), an important aspect not considered in the original Jacobson–Stockmayer theory of reversible polycondensations.
Publikováno v:
Polymer Chemistry. 13:1618-1647
Reaction mechanisms and synthetic methods used for the preparation of homo- and copolylactides based on tin(ii) and tin(iv) catalysts are reviewed.
Publikováno v:
Journal of Polymer Science. 60:785-793
Publikováno v:
Journal of Polymer Science. 59:439-450
The catalytic potential of tin(II)acetate, tin(IV)acetate, dibutyltin-bis-acetate and dioctyl tin-bis-acetate was compared based on polymerizations of L-lactide conducted in bulk at 160 or 130C. With SnAc2 low-Lac/Cat ratios (15/1–50/1) were stu
Publikováno v:
Journal of Polymers and the Environment. 29:2504-2516
Polymerizations of l-lactide catalyzed either by neat SnCl2 or by SnCl2 + difunctional cocatalysts were conducted in bulk at 180, 160 and 140 °C with variation of the Lac/Cat ratio and time. With neat SnCl2 poly(L-lactide) having weight average mole
Publikováno v:
RSC Advances. 11:14093-14102
Alcohol-initiated ROPs of L-lactide were performed in bulk at 160 °C for 72 h with variation of the catalyst or with variation of the initiator (aliphatic alcohols). Spontaneous crystallization was only observed when cyclic Sn(II) compounds were use
Publikováno v:
RSC Advances. 11:2872-2883
Cyclic polylactides were prepared in bulk at 170 °C, crystallized at 120 °C and then annealed at temperatures between 130 and 170 °C with variation of catalyst, catalyst concentration and annealing time. The transformation of the initially formed